CASWELL INC
Safety Data Sheet
Swab On Copper Blackener
SECTION 1: Identification
1.1 Product identifier
Product name Swab On Copper Blackener
Product number A324
Brand CASWELL
1.2 Other means of identification
Blue liquid
1.4 Supplier's details
Name Caswell Inc
Address 7696 Route 31
Lyons NY 14489
USA
Telephone 315 946 1213
Fax 315 946 4456
email sales@caswellplating.com
1.5 Emergency phone number(s)
Office Hours (9-4ET): 315 946 1213
24 Hour: CHEMTEL US# 1-800-255-3924 Intl# +01-813-248-0585
SECTION 2: Hazard identification
2.1 Classification of the substance or mixture
- Eye damage/irritation (chapter 3.3), Cat. 2A
- Hazardous to the aquatic environment - long-term hazard (chapter 4.1), Cat. 3
- Hazardous to the aquatic environment - acute hazard (chapter 4.1), Cat. 1
2.2 GHS label elements, including precautionary statements
Pictogram
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Safety Data Sheet
Swab On Copper Blackener
Signal word Warning
Hazard statement(s)
H318 Causes serious eye damage
H402 Harmful to aquatic life
H412 Harmful to aquatic life with long lasting effects
H319 Causes serious eye irritation
H400 Very toxic to aquatic life
Precautionary statement(s)
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P363 Wash contaminated clothing before reuse.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P310 Immediately call a POISON CENTER/doctor/...
P321 Specific treatment (see info on this label).
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses if present and easy to do. Continue rinsing.
P405 Store locked up.
P501 Dispose of contents/container per local regulations
P270 Do not eat, drink or smoke when using this product.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/...
P330 Rinse mouth.
P273 Avoid release to the environment.
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P391 Collect spillage.
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Hazardous components
1. WATER OR OTHER NON-REPORTABLE INGREDIENTS
Concentration < 74 - 74 % (weight)
CAS no. 7732-18-5
2. Phosphoric acid liquid
Concentration < 10 - 10 % (weight)
EC no. 231-633-2
CAS no. 7664-38-2
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Swab On Copper Blackener
Index no. 015-011-00-6
- Skin corrosion/irritation (chapter 3.2), Cat. 1B
H314 Causes severe skin burns and eye damage
3. Methanol
Concentration < 7 - 7 % (weight)
EC no. 200-659-6
CAS no. 67-56-1
Index no. 603-001-00-X
- Flammable liquids (chapter 2.6), Cat. 2
- Acute toxicity (chapter 3.1), Cat. 3
- Specific target organ toxicity following single exposure (chapter 3.8), Cat. 1
H225 Highly flammable liquid and vapor
H301 Toxic if swallowed
H311 Toxic in contact with skin
H331 Toxic if inhaled
H370 Causes damage to organs [organs, route]
4. MOLYBDENUM TRIOXIDE
Concentration < 3 - 3 % (weight)
EC no. 215-204-7
CAS no. 1313-27-5
Index no. 042-001-00-9
- Specific target organ toxicity following repeated exposure (chapter 3.9), Cat. 2
- Serious eye damage/eye irritation (chapter 3.3), Cat. 2
- Specific target organ toxicity following single exposure (chapter 3.8), Cat. 3
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H373 May cause damage to organs [organs] through prolonged or repeated
exposure [route]
5. Copper powder
Concentration < 4 - 6 % (weight)
CAS no. 7440-50-8
6. SELENIOUS ACID
Concentration < 2 - 3 % (weight)
CAS no. 7783-00-8
SECTION 4: First-aid measures
4.1 Description of necessary first-aid measures
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Safety Data Sheet
Swab On Copper Blackener
General advice Substance can cause severe skin, eye and respiratory tract irritation/nurning.
Corrosive. Will cause eye burns and permanent tissue damage.
If inhaled If breathed in, move person into fresh air. If not breathing, give artificial
respiration. Consult a physician.
In case of skin contact Wash off with soap and plenty of water. Consult a physician.
In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a
physician.
If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious
person. Rinse mouth with water. Consult a physician.
SECTION 5: Fire-fighting measures
5.1 Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Specific hazards arising from the chemical
May produce toxic selenious fumes. Reactions with organics and strong reducing agents can produce volatile
organoselenides or hydrogen selenide.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
SMALL SPILLS: Contain and absorb with absorbent material and place into containers for later disposal. Wash site
of spillage thoroughly with water. LARGE SPILLS: Dike far ahead of spill to prevent further movement. Recover by
pumping or by using a suitable absorbent material and place into containers for later disposal. Dispose in suitable
waste container.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully
resealed and kept upright to prevent leakage.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
1. Copper, Fume (as Cu) (CAS: 7440-50-8)
PEL (Inhalation): 0.1 mg/m3 (OSHA)
OSHA Annotated Table Z-1, www.osha.gov
PEL (Inhalation): 0.1 mg/m3 (Cal/OSHA)
OSHA Annotated Table Z-1, www.osha.gov
REL (Inhalation): 0.1 mg/m3 (NIOSH)
OSHA Annotated Table Z-1, www.osha.gov
2. Copper, Dusts and mists (as Cu) (CAS: 7440-50-8)
PEL (Inhalation): 1 mg/m3 (OSHA)
OSHA Annotated Table Z-1, www.osha.gov
PEL (Inhalation): 1 mg/m3 (Cal/OSHA)
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Swab On Copper Blackener
OSHA Annotated Table Z-1, www.osha.gov
REL (Inhalation): 1 mg/m3 (NIOSH)
OSHA Annotated Table Z-1, www.osha.gov
3. Phosphoric acid (CAS: 7664-38-2)
PEL (Inhalation): 1 mg/m3 (OSHA)
OSHA Annotated Table Z-1, www.osha.gov
PEL (Inhalation): 1 mg/m3, (ST) 3 mg/m3 (Cal/OSHA)
OSHA Annotated Table Z-1, www.osha.gov
REL (Inhalation): 1 mg/m3, (ST) 3 mg/m3 (NIOSH)
OSHA Annotated Table Z-1, www.osha.gov
4. METHYL ALCOHOL (CAS: 67-56-1 EC: 200-659-6)
PEL-TWA: 200 ppm (ACGIH)
Headache, Nausea, Dizziness, Eye damage Substances for which there is a Biological Exposure Index or Indices
(see BEI® section) Danger of cutaneous absorption
STEL: 250 ppm (ACGIH)
PEL-TWA: 200 ppm, 325 mg/m3 (NIOSH)
Potential for dermal absorption
PEL-TWA: 200 ppm, 260 mg/m3 (OSHA)
USA. Occupational Exposure Limits
(OSHA) - Table Z-1 Limits for Air
Contaminants
PEL (Inhalation): 200 ppm (OSHA)
OSHA Annotated Table Z-1, www.osha.gov
PEL (Inhalation): 260 mg/m3 (OSHA)
OSHA Annotated Table Z-1, www.osha.gov
PEL (Inhalation): 200 ppm, (ST) 250 ppm, (C) 1000 ppm (Cal/OSHA)
OSHA Annotated Table Z-1, www.osha.gov
REL (Inhalation): 200 ppm, (ST) 250 ppm (NIOSH)
OSHA Annotated Table Z-1, www.osha.gov
8.3 Individual protection measures, such as personal protective equipment (PPE)
Pictograms
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH
(US) or EN 166(EU).
Skin protection
Wear chemical resistant gloves and clothing.
Respiratory protection
NIOSH/MSHA approved air purifying respirator with an organic vapor cartidge or canister may be permissable
under certain circumstances where airborne concentrations are expected to exceed exposure limits.
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Swab On Copper Blackener
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Appearance/form (physical state, color, etc.) Blue Liquid
Odor Odorless
Odor threshold
pH 1.68
Melting point/freezing point
Initial boiling point and boiling range 212 deg F
Flash point
Evaporation rate 1
Flammability (solid, gas)
Upper/lower flammability limits
Vapor pressure 20
Vapor density Approx equal to water
Relative density 1.055
Solubility(ies) Soluble In Water
Partition coefficient: n-octanol/water
Auto-ignition temperature
Decomposition temperature
Viscosity
Explosive properties
Oxidizing properties
SECTION 10: Stability and reactivity
10.2 Chemical stability
Stable
10.5 Incompatible materials
Cyanides, organic solvents, strong reducing agents
SECTION 11: Toxicological information
Information on toxicological effects
Acute toxicity
not available
SECTION 12: Ecological information
Toxicity
not available
SECTION 13: Disposal considerations
Disposal of the product
Consult appropriate federal and local regulations for disposal. Empty containers are subject to the same regulations.
SECTION 14: Transport information
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Safety Data Sheet
Swab On Copper Blackener
DOT (US)
UN Number: UN1760
Class: 8
Packing Group: II
Proper Shipping Name: Corrosive Liquid, NOS (Phosphoric Acid, Selenious Acid)
Reportable quantity (RQ): 335 lbs
Small quantities may be shipped as Limited Quantities. Consult 49 CFR.
IMDG
UN Number:
Class:
Packing Group:
EMS Number:
Proper Shipping Name:
IATA
UN Number: UN1760
Class: 8
Packing Group: II
Proper Shipping Name: Corrosive Liquid, NOS (Phosphoric Acid, Selenious Acid)
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations specific for the product in question
Massachusetts Right To Know Components
Chemical name: Selenious acid
CAS number: 7783-00-8
New Jersey Right To Know Components
Common name: SELENOUS ACID
CAS number: 7783-00-8
Pennsylvania Right To Know Components
Chemical name: Selenous acid
CAS number: 7783-00-8
Massachusetts Right To Know Components
Chemical name: Copper
CAS number: 7440-50-8
New Jersey Right To Know Components
Common name: COPPER
CAS number: 7440-50-8
Pennsylvania Right To Know Components
Chemical name: Copper
CAS number: 7440-50-8
Massachusetts Right To Know Components
Chemical name: Nitric acid
CAS number: 7697-37-2
New Jersey Right To Know Components
Common name: NITRIC ACID
CAS number: 7697-37-2
Pennsylvania Right To Know Components
Chemical name: Nitric acid
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Swab On Copper Blackener
CAS number: 7697-37-2
Massachusetts Right To Know Components
Chemical name: Phosphoric acid
CAS number: 7664-38-2
New Jersey Right To Know Components
Common name: PHOSPHORIC ACID
CAS number: 7664-38-2
Massachusetts Right To Know Components
Chemical name: Methanol
CAS number: 67-56-1
New Jersey Right To Know Components
Common name: METHYL ALCOHOL
CAS number: 67-56-1
Pennsylvania Right To Know Components
Chemical name: Methanol
CAS number: 67-56-1
California Prop. 65 components
Chemical name: Methanol
CAS number: 67-56-1
03/16/2012 - Developmental toxicity
Massachusetts Right To Know Components
Chemical name: Molybdenum trioxide
CAS number: 1313-27-5
New Jersey Right To Know Components
Common name: MOLYBDENUM TRIOXIDE
CAS number: 1313-27-5
Pennsylvania Right To Know Components
Chemical name: Molybdenum trioxide
CAS number: 1313-27-5
HMIS Rating
Swab On Copper Blackener
HEALTH *2
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION C
NFPA Rating
SECTION 16: Other information
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Swab On Copper Blackener
16.1 Further information/disclaimer
DISCLAIMER: The information above is believed to be accurate and represents the best information currently
available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with
respect to such information, and we assume no liability resulting from its use. Users should make their own
investigation to determine the suitability of information for their particular purposes. In no event shall Caswell Inc be
liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental,
consequential or exemplary damages, whatsoever arising, even if Caswell Inc has been advised of the possibility of
such damages.
16.2 Preparation information
L CASWELL
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