ALUMINUM BRIGHTENER

ALUMINUM BRIGHTENER

                                                                               CASWELL INC

Safety Data Sheet
Aluminum Brightener
SECTION 1: Identification

1.1   Product identifier

      Product name                            Aluminum Brightener

      Product number                          ALBR
      Brand                                   CASWELL

1.4   Supplier's details

      Name                                    Caswell Inc
      Address                                 7696 Route 31
                                              Lyons NY 14489
                                              USA

      Telephone                               315 946 1213
      Fax                                     315 946 4456
      email                                   sales@caswellplating.com

1.5   Emergency phone number(s)

                                              Office Hours (9-4ET): 315 946 1213
                                              24 Hour: CHEMTEL US# 1-800-255-3924    Intl# +01-813-248-0585

SECTION 2: Hazard identification

2.1   Classification of the substance or mixture

      - Acute toxicity, inhalation (chapter 3.1), Cat. 2
      - Acute toxicity, dermal (chapter 3.1), Cat. 2
      - Skin corrosion/irritation (chapter 3.2), Cat. 1A

2.2   GHS label elements, including precautionary statements

      Pictogram




      Signal word                             Danger


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Aluminum Brightener

      Hazard statement(s)
      H330                                     Fatal if inhaled
      H310                                     Fatal in contact with skin
      H314                                     Causes severe skin burns and eye damage

      Precautionary statement(s)
      P260                                     Do not breathe dust/fume/gas/mist/vapours/spray.
      P271                                     Use only outdoors or in a well-ventilated area.
      P284                                     [In case of inadequate ventilation] wear respiratory protection.
      P304+P340                                IF INHALED: Remove person to fresh air and keep comfortable for breathing.
      P310                                     Immediately call a POISON CENTER/doctor/...
      P320                                     Specific treatment is urgent (see … on this label).
      P403+P233                                Store in a well ventilated place. Keep container tightly closed.
      P405                                     Store locked up.
      P501                                     Dispose of contents/container to …
      P262                                     Do not get in eyes, on skin, or on clothing.
      P264                                     Wash … thoroughly after handling.
      P270                                     Do not eat, drink or smoke when using this product.
      P280                                     Wear protective gloves/protective clothing/eye protection/face protection.
      P302+P352                                IF ON SKIN: Wash with plenty of water/...
      P321                                     Specific treatment (see … on this label).
      P361+P364                                Take off immediately all contaminated clothing and wash it before reuse.
      P301+P330+P331                           IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
      P303+P361+P353                           IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
                                               skin with water/shower.
      P363                                     Wash contaminated clothing before reuse.
      P305+P351+P338                           IF IN EYES: Rinse cautiously with water for several minutes. Remove
                                               contact lenses if present and easy to do. Continue rinsing.

SECTION 3: Composition/information on ingredients

3.2   Mixtures

      Hazardous components

      1. Phosphoric acid liquid
      Concentration                            < 10 %
      EC no.                                   231-633-2
      CAS no.                                  7664-38-2
      Index no.                                015-011-00-6

      - Skin corrosion/irritation (chapter 3.2), Cat. 1B

      H314                                     Causes severe skin burns and eye damage


      2. HYDROFLUORIC ACID
      Concentration                            < 15 %
      EC no.                                   231-634-8
      CAS no.                                  7664-39-3
      Index no.                                009-003-00-1

      - Acute toxicity (chapter 3.1), Cat. 2
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Aluminum Brightener
      - Acute toxicity (chapter 3.1), Cat. 1
      - Skin corrosion/irritation (chapter 3.2), Cat. 1A

      H300                                     Fatal if swallowed
      H310                                     Fatal in contact with skin
      H314                                     Causes severe skin burns and eye damage
      H330                                     Fatal if inhaled


      Trade secret statement (OSHA 1910.1200(i))
      Specfic Non Hazardous and Non Reportabale Chemical Compounds and Percentages Have Been Omitted As A
      Trade Secret under OSHA 1910.1200(i)

SECTION 4: First-aid measures

4.1   Description of necessary first-aid measures

      General advice                           Corrosive to skin and mucous membranes.

      If inhaled                               If breathed in, move person into fresh air. If not breathing, give artificial
                                               respiration. Consult a physician.

      In case of skin contact                  Wash off with soap and plenty of water. Get medical attention if symptoms
                                               occur.

      In case of eye contact                   Rinse thoroughly with plenty of water for at least 15 minutes and consult a
                                               physician.

      If swallowed                             Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical
                                               attention immediately if symptoms occur.

      Personal protective equipment for first-aid responders
                                              See section 8

4.2   Most important symptoms/effects, acute and delayed
      not available

SECTION 5: Fire-fighting measures

5.1   Suitable extinguishing media
      Dry chemical, foam, carbon dioxide, water fog.

5.2   Specific hazards arising from the chemical
      Contact with some metals, particularly magnesium, aluminum and zinc (galvanized) can rapidly generate hydrogen,
      which can be explosive.

5.3   Special protective actions for fire-fighters
      Wear self-contained breathing apparatus for firefighting if necessary.

SECTION 6: Accidental release measures

6.1   Personal precautions, protective equipment and emergency procedures
      SMALL SPILLS: Contain and absorb with absorbent material and place into containers for later disposal. Wash site
      of spillage thoroughly with water. LARGE SPILLS: Dike far ahead of spill to prevent further movement. Recover by

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Aluminum Brightener
      pumping or by using a suitable absorbent material and place into containers for later disposal. Dispose in suitable
      waste container.

6.2   Environmental precautions
      Toxic To Aquatic Life. Avoid release to environment.

6.3   Methods and materials for containment and cleaning up
      Do not allow to enter drains or water source.

SECTION 7: Handling and storage

7.1   Precautions for safe handling
      Keep container tightly closed in a dry and well-ventilated place.

7.2   Conditions for safe storage, including any incompatibilities
      not available

SECTION 8: Exposure controls/personal protection

8.1   Control parameters

      1. Phosphoric acid (CAS: 7664-38-2)
      PEL (Inhalation): 1 mg/m3 (OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      PEL (Inhalation): 1 mg/m3, (ST) 3 mg/m3 (Cal/OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      REL (Inhalation): 1 mg/m3, (ST) 3 mg/m3 (NIOSH)
      OSHA Annotated Table Z-1, www.osha.gov

8.2   Appropriate engineering controls
      Avoid exposure.

8.3   Individual protection measures, such as personal protective equipment (PPE)

      Pictograms




      Eye/face protection
      Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate
      government standards such as NIOSH (US) or EN 166(EU).

      Skin protection
      Wear chemical resistant gloves and clothing.

      Respiratory protection
      Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose
      combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the
      respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components
      tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

SECTION 9: Physical and chemical properties
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Aluminum Brightener

     Information on basic physical and chemical properties

     Appearance/form (physical state, color, etc.)           Clear Liquid
     Odor                                                    Acidic
     Odor threshold                                          not available
     pH                                                      <2
     Melting point/freezing point                            not available
     Initial boiling point and boiling range                 220 deg F
     Flash point                                             None
     Evaporation rate                                        not available
     Flammability (solid, gas)                               not available
     Upper/lower flammability limits                         not available
     Upper/lower explosive limits                            not available
     Vapor pressure                                          not available
     Vapor density                                           not available
     Relative density                                        1.06
     Solubility(ies)                                         Complete in Water
     Partition coefficient: n-octanol/water                  not available
     Auto-ignition temperature                               not available
     Decomposition temperature                               not available
     Viscosity                                               not available
     Explosive properties
     Oxidizing properties

SECTION 10: Stability and reactivity

10.1 Reactivity
     Not Reactive

10.2 Chemical stability
     Material is Stable

10.3 Possibility of hazardous reactions
     None

10.4 Conditions to avoid
     None

10.5 Incompatible materials
     Strong Acids

SECTION 11: Toxicological information

     Information on toxicological effects

     Acute toxicity
     Not established

     Skin corrosion/irritation
     Not established

     Serious eye damage/irritation
     Not established

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Aluminum Brightener

    Respiratory or skin sensitization
    Not established

    Germ cell mutagenicity
    Not established

    Carcinogenicity
    None

    Reproductive toxicity
    Not established

    STOT-single exposure
    Not established

    STOT-repeated exposure
    Not established

    Aspiration hazard
    Not established

SECTION 12: Ecological information

    Toxicity
    Harmful to aquatic life.

    Persistence and degradability
    Not established

    Bioaccumulative potential
    Not established

    Mobility in soil
    Not established

    Results of PBT and vPvB assessment
    Not established

SECTION 13: Disposal considerations

    Disposal of the product
    SMALL SPILLS: Contain and absorb with absorbent material and place into containers for later disposal. Wash site
    of spillage thoroughly with water. LARGE SPILLS: Dike far ahead of spill to prevent further movement. Recover by
    pumping or by using a suitable absorbent material and place into containers for later disposal. Dispose in suitable
    waste container.

    Disposal of contaminated packaging
    Dispose of as unused product.

    Waste treatment
    Not established

    Sewage disposal

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Aluminum Brightener
     Not established

SECTION 14: Transport information

     DOT (US)
     UN Number: UN1760
     Class: 8
     Packing Group: II
     Proper Shipping Name: Corrosive liquid, NOS (Hydroflouric Acid, Phosphoric Acid)
     Reportable quantity (RQ):
     Marine pollutant:
     Poison inhalation hazard:
     Small Quantities may be shipped as LTD QTY.

     IMDG
     UN Number: UN1760
     Class: 8
     Packing Group: II
     EMS Number:
     Proper Shipping Name: Corrosive liquid, NOS (Hydroflouric Acid, Phosphoric Acid)

     IATA
     UN Number: UN1760
     Class: 8
     Packing Group: II
     Proper Shipping Name: Corrosive liquid, NOS (Hydroflouric Acid, Phosphoric Acid)

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question
     Massachusetts Right To Know Components
     Chemical name: Phosphoric acid
     CAS number: 7664-38-2
     New Jersey Right To Know Components
     Common name: PHOSPHORIC ACID
     CAS number: 7664-38-2
     Massachusetts Right To Know Components
     Chemical name: Hydrofluoric acid
     CAS number: 7664-39-3
     New Jersey Right To Know Components
     Common name: HYDROGEN FLUORIDE
     CAS number: 7664-39-3
     Pennsylvania Right To Know Components
     Chemical name: Hydrofluoric acid
     CAS number: 7664-39-3

     HMIS Rating

              Aluminum Brightener
       HEALTH                         *2
       FLAMMABILITY                    0


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Aluminum Brightener
        PHYSICAL HAZARD                    0
        PERSONAL PROTECTION               C


      NFPA Rating




SECTION 16: Other information

16.1 Further information/disclaimer
     DISCLAIMER: The information above is believed to be accurate and represents the best information currently
     available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with
     respect to such information, and we assume no liability resulting from its use. Users should make their own
     investigation to determine the suitability of information for their particular purposes. In no event shall Caswell Inc be
     liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental,
     consequential or exemplary damages, whatsoever arising, even if Caswell Inc has been advised of the possibility of
     such damages.




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