Aluminum Degreaser

Aluminum Degreaser

                                                                              CASWELL INC

Safety Data Sheet
Aluminum Degreaser
SECTION 1: Identification

1.1   Product identifier

      Product name                           Aluminum Degreaser

      Product number                         ALDG
      Brand                                  Caswell

1.4   Supplier's details

      Name                                   Caswell Inc
      Address                                7696 Route 31
                                             Lyons NY 14489
                                             USA

      Telephone                              315 946 1213
      Fax                                    315 946 4456
      email                                  sales@caswellplating.com

1.5   Emergency phone number(s)

                                             Office Hours (9-4ET): 315 946 1213
                                             24 Hour: CHEMTEL US# 1-800-255-3924    Intl# +01-813-248-0585

SECTION 2: Hazard identification

2.1   Classification of the substance or mixture

      - Toxic to reproduction (chapter 3.7), Cat. 2
      - Eye damage/irritation (chapter 3.3), Cat. 2
      - Acute toxicity, oral (chapter 3.1), Cat. 5

2.2   GHS label elements, including precautionary statements

      Pictogram




      Signal word                            Warning


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Aluminum Degreaser

      Hazard statement(s)
      H361                               Suspected of damaging fertility or the unborn child
      H319                               Causes serious eye irritation
      H303                               May be harmful if swallowed

      Precautionary statement(s)
      P201                               Obtain special instructions before use.
      P202                               Do not handle until all safety precautions have been read and understood.
      P280                               Wear protective gloves/protective clothing/eye protection/face protection.
      P308+P313                          IF exposed or concerned: Get medical advice/attention.
      P405                               Store locked up.
      P501                               Dispose of contents/container to …
      P264                               Wash … thoroughly after handling.
      P305+P351+P338                     IF IN EYES: Rinse cautiously with water for several minutes. Remove
                                         contact lenses if present and easy to do. Continue rinsing.
      P337+P313                          If eye irritation persists: Get medical advice/attention.
      P312                               Call a POISON CENTER/doctor/... if you feel unwell.

SECTION 3: Composition/information on ingredients

3.1   Substances

      Hazardous components

      1. Sodium Tetraborate Decahydrate
      Concentration                     40 - 50 %
      CAS no.                           1303-96-4

      2. OTHER NON-REPORTABLE INGREDIENTS
      Concentration               40 - 50 %

SECTION 4: First-aid measures

4.1   Description of necessary first-aid measures

      General advice                     Observation only is required for adult ingestion of less than 7 grams of borax
                                         decahydrate. For ingestion in excess of 7 grams, maintain adequate kidney
                                         function and force fluids.
                                         Gastric lavage is recommended for symptomatic patients only. Hemodialysis
                                         should be reserved for
                                         massive acute ingestion or patients with renal failure. Boron analyses of
                                         urine or blood are only useful for
                                         documenting exposure and should not be used to evaluate severity of
                                         poisoning or to guide
                                         treatment (see section 11).

      If inhaled                         If symptoms such as nose or throat irritation are observed, remove person to
                                         fresh air. If not
                                         breathing, give artificial respiration. Seek medical attention.

      In case of skin contact            Wash with soap and water. Seek medical attention.



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Aluminum Degreaser
      In case of eye contact                  As with any chemical exposure to the eye, flush eyes with water for at least
                                              20-minutes.
                                              Seek medical attention.

      If swallowed                            If large amounts are swallowed (i.e. more than one teaspoon), give two
                                              glasses of water or
                                              milk to drink and seek medical attention. Never give anything by mouth to an
                                              unconscious person.

SECTION 5: Fire-fighting measures

5.1   Suitable extinguishing media
      Use fire extinguishing media suitable for surrounding fires.

5.2   Specific hazards arising from the chemical
      None – Borax is non-flammable, combustible or explosive. The
      product is itself a flame retardant.

5.3   Special protective actions for fire-fighters
      Firefighters should wear pressure demand, self-contained breathing
      apparatus and full turn-out gear.

SECTION 6: Accidental release measures

6.1   Personal precautions, protective equipment and emergency procedures
      Avoid dust formation. In case of exposure to prolonged or high level of airborne
      dust, wear a personal respirator in compliance with national legislation.

6.2   Environmental precautions
      Borax decahydrate is a water-soluble white powder that may, at high
      concentrations cause damage to trees or vegetation by root absorption (see section 12)

6.3   Methods and materials for containment and cleaning up
      Land spill : Vacuum, shovel or sweep up borax and place in containers for disposal in accordance with
      applicable local regulations. Avoid contamination of water bodies during clean up and disposal. No
      personal protective equipment is needed to clean up land spills.
      Spillage into water : Where possible, remove any intact containers from the water. Advise local water
      authority that none of the affected water should be used for irrigation or for the abstraction of potable
      water until natural dilution returns the boron value to its normal environmental background level (see
      sections 12, 13 and 15).

SECTION 7: Handling and storage

7.1   Precautions for safe handling
      To maintain package integrity and to minimize caking of the product, bags should be handled
      on a first-in first out basis. Good housekeeping and dust prevention procedures should be followed to
      minimize dust generation and accumulation. Your supplier can advise you on safe handling, please
      contact the supplier. The product should be kept away from strong
      reducing agents. Apply above handling advice when mixing with other substances.

7.2   Conditions for safe storage, including any incompatibilities
      Keep containers closed and store indoors in a dry well ventilated location.
      Provide appropriate ventilation and store bags such as to prevent any accidental damage.


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Safety Data Sheet
Aluminum Degreaser
SECTION 8: Exposure controls/personal protection

8.1   Control parameters

      1. Sodium Tetraborate Decahydrate (CAS: 1303-96-4)
      TLV®: 5 (ACGIH)

8.2   Appropriate engineering controls
      Maintain air concentrations below occupational exposure standards.
      Ventilation / Local Exhaust / Mechanical Recommendations: Use local exhaust ventilation

8.3   Individual protection measures, such as personal protective equipment (PPE)

      Pictograms




      Eye/face protection
      Goggles or face shield.

      Skin protection
      Vinyl or rubber protective gloves.

      Body protection
      Vinyl apron (optional).

      Respiratory protection
      Where risk assessment shows air-purifying respirators are appropriate
      use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a
      backup to engineering controls. If the respirator is the sole means of protection, use a full-face
      supplied air respirator. Use respirators and components tested and approved under appropriate
      government standards such as NIOSH (US) or CEN (EU).

SECTION 9: Physical and chemical properties

      Information on basic physical and chemical properties

      Appearance/form (physical state, color, etc.)               White granular powder
      Odor                                                        None
      Odor threshold                                              NA
      pH                                                          9 - 10
      Melting point/freezing point                                NA
      Initial boiling point and boiling range                     NA
      Flash point                                                 NA
      Evaporation rate                                            NA
      Flammability (solid, gas)                                   NA
      Upper/lower flammability limits                             NA
      Vapor pressure                                              NA
      Vapor density
      Relative density                                            NA
      Solubility(ies)                                             Complete in water
      Partition coefficient: n-octanol/water                      NA
      Auto-ignition temperature                                   NA

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Safety Data Sheet
Aluminum Degreaser
      Decomposition temperature                                   NA
      Viscosity                                                   NA
      Explosive properties                                        NA
      Oxidizing properties                                        NA

      Other safety information
      Product does not contain Volatile Organic Compounds

SECTION 10: Stability and reactivity

10.2 Chemical stability
     Borax decahydrate is stable under normal ambient and anticipated storage and
     handling conditions of temperature and pressure. When heated it losses water, eventually forming
     anhydrous borax (Na2 B4 O7 ).

10.4 Conditions to avoid
     Exposure to moisture and incompatible materials.

10.5 Incompatible materials
     Avoid contact with strong reducing agents such as metal
     hydrides, acetic anhydride or alkali metals. Reaction with strong reducing agents such as metal
     hydrides, acetic anhydride or alkali metals will generate flammable hydrogen gas which could create an
     explosive hazard.

10.6 Hazardous decomposition products
     Boranes, hydrogen, boron oxides.

SECTION 11: Toxicological information

      Information on toxicological effects

      Acute toxicity
      Low acute oral toxicity; LD50 in rats is 6,000 mg/kg of body weight.

      Skin corrosion/irritation
      Low acute dermal toxicity; LD50 in rabbits is greater than 2,000 mg/kg of body
      weight. Borax decahydrate is poorly absorbed through intact skin. Non-irritant.

      Serious eye damage/irritation
      Borax decahydrate is a serious eye irritant.

      Respiratory or skin sensitization
      Borax is not a skin sensitizer.

      Germ cell mutagenicity
      This product does not contain any materials considered to be
      carcinogenous according to OSHA, NTP, IARC, or ACGIH.

      Reproductive toxicity
      Animal feeding studies in rat, mouse and dog, at high doses, have demonstrated
      effects on fertility and testes (2). Studies with chemically related boric acid in rat, mouse and rabbit, at
      high doses, demonstrate developmental effects on the fetus including fetal weight loss and minor skeletal
      variations. The doses administered were many times in excess of those
      which humans would normally be exposed to. Human epidemiological studies show no increase in

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Safety Data Sheet
Aluminum Degreaser
     pulmonary disease in occupational populations with chronic exposures to boric acid dust and sodium
     borate dust. A recent epidemiology study under the conditions of normal occupational exposure to borate
     dusts indicated no effect on fertility.

SECTION 12: Ecological information

     Toxicity
     Boron is an essential micronutrient for healthy growth of plants; however, it can be
     harmful to boron sensitive plants in higher quantities. Care should be taken to minimize the amount of
     borate product released to the environment.
     Algal toxicity : Green algae, Pseudokirchneriella subcapitata (Hansveit and Oldersma, 2000)
     72-hr EC50 –biomass = 40 mg B/L, or 229 mg boric acid/L.
     Invertebrate toxicity : Daphnia, Daphnids, Daphnia magna (Gersich, 1984a)
     48-hr LC50 = 133 mg B/L or 760 mg boric acid/L or 619 mg disodium tetraborate , anhydrous/L
     Fish toxicity : Fish, Fathered minnow, Pimephales promelas (Soucek et al., 2010)
     96-hr LC50 = 79.7 mg B/L or 456 mg boric acid/L or 370 mg disodium tetraborate, anhydrous

SECTION 13: Disposal considerations

     Disposal of the product
     Recycle, recovery and reuse of materials, where permitted, is encouraged as
     an alternate to disposal as a waste. Hazardous waste classification under federal regulations (40 CFR
     Part 261 et seq) is dependent upon whether a material is a RCRA listed hazardous waste or has any of
     the four RCRA hazardous waste characteristics. Refer to 40 CFR Part 261.33 to determine if a given
     material to be disposed of is a RCRA listed hazardous waste. RCRA Hazardous Waste Characteristics:
     There are four characteristics defined in 40 CFR Section 261.21-61.24: Ignitability, Corrosivity, Reactivity,
     and Toxicity. To determine Ignitability, see Section 9 of this SDS (flash point). For Corrosivity, see
     Sections 9 and 14 (pH and DOT corrosivity). For Reactivity, see Section 10 (incompatible materials). For
     Toxicity, see Section 2 (composition). Federal regulations are subject to change. State and local
     requirements, which may differ from or be more stringent than the federal regulations, may also apply to
     the classification of the material if it is to be disposed.

SECTION 14: Transport information

     DOT (US)
     Not dangerous goods

     IMDG
     Not dangerous goods

     IATA
     Not dangerous goods

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question
     Pennsylvania Right To Know Components
     Chemical name: Borax
     CAS number: 1303-96-4
     Toxic Substances Control Act (TSCA) Inventory
     Chemical name: Borax
     CAS number: 1303-96-4


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Safety Data Sheet
Aluminum Degreaser
      HMIS Rating

                Aluminum Degreaser
        HEALTH                             2
        FLAMMABILITY                       0
        PHYSICAL HAZARD                    0
        PERSONAL PROTECTION                F


      NFPA Rating




SECTION 16: Other information

16.1 Further information/disclaimer
     DISCLAIMER: The information above is believed to be accurate and represents the best information currently
     available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with
     respect to such information, and we assume no liability resulting from its use. Users should make their own
     investigation to determine the suitability of information for their particular purposes. In no event shall Caswell Inc be
     liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental,
     consequential or exemplary damages, whatsoever arising, even if Caswell Inc has been advised of the possibility of
     such damages.




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