CASWELL INC
Safety Data Sheet
Anodize Touch Up Solution
SECTION 1: Identification
1.1 Product identifier
Product name Anodize Touch Up Solution
Product number ARL4
Brand CASWELL
1.3 Recommended use of the chemical and restrictions on use
Metal Blackening of Aluminum
1.4 Supplier's details
Name Caswell Inc
Address 7696 Route 31
Lyons NY 14489
USA
Telephone 315 946 1213
Fax 315 946 4456
email sales@caswellplating.com
1.5 Emergency phone number(s)
Office Hours (9-4ET): 315 946 1213
24 Hour: CHEMTEL US# 1-800-255-3924 Intl# +01-813-248-0585
SECTION 2: Hazard identification
2.1 Classification of the substance or mixture
- Skin corrosion/irritation (chapter 3.2), Cat. 2
- Eye damage/irritation (chapter 3.3), Cat. 2A
- Carcinogenicity (chapter 3.6), Cat. 1A
- Hazardous to the aquatic environment - long-term hazard (chapter 4.1), Cat. 3
- Hazardous to the aquatic environment - acute hazard (chapter 4.1), Cat. 3
2.2 GHS label elements, including precautionary statements
Pictogram
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Safety Data Sheet
Anodize Touch Up Solution
Signal word Danger
Hazard statement(s)
H350 May cause cancer
H412 Harmful to aquatic life with long lasting effects
H402 Harmful to aquatic life
H319 Causes serious eye irritation
H315 Causes skin irritation
Precautionary statement(s)
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P363 Wash contaminated clothing before reuse.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P310 Immediately call a POISON CENTER/doctor/...
P321 Specific treatment (see info on this label).
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses if present and easy to do. Continue rinsing.
P405 Store locked up.
P501 Dispose of contents/container per local regulations
P270 Do not eat, drink or smoke when using this product.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/...
P330 Rinse mouth.
P273 Avoid release to the environment.
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P332+P313 If skin irritation occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Hazardous components
1. WATER
Concentration 85 - 95 %
CAS no. 7732-18-5
2. Ammonium dimolybdate
Concentration 3%
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Safety Data Sheet
Anodize Touch Up Solution
CAS no. 27546-07-2
3. SELENIOUS ACID
Concentration 1-4%
CAS no. 7783-00-8
4. COPPER SULFATE PENTAHYDRATE
Concentration 3%
CAS no. 7758-99-8
5. Sulfuric acid (<10%)
Concentration 3%
EC no. 231-639-5
CAS no. 7664-93-9
Index no. 016-020-00-8
- Skin corrosion/irritation (chapter 3.2), Cat. 1A
H314 Causes severe skin burns and eye damage
SECTION 4: First-aid measures
4.1 Description of necessary first-aid measures
General advice Substance can cause cancer.
If inhaled If breathed in, move person into fresh air. If not breathing, give artificial
respiration. Consult a physician.
In case of skin contact Wash off with soap and plenty of water. Consult a physician.
In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a
physician.
If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious
person. Rinse mouth with water. Consult a physician.
Personal protective equipment for first-aid responders
See section 8
SECTION 5: Fire-fighting measures
5.1 Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Specific hazards arising from the chemical
May produce toxic selenious fumes. Reactions with organics and strong reducing agents can produce volatile
organoselenides or hydrogen selenide.
SECTION 6: Accidental release measures
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Safety Data Sheet
Anodize Touch Up Solution
6.1 Personal precautions, protective equipment and emergency procedures
SMALL SPILLS: Contain and absorb with absorbent material and place into containers for later disposal. Wash site
of spillage thoroughly with water. LARGE SPILLS: Dike far ahead of spill to prevent further movement. Recover by
pumping or by using a suitable absorbent material and place into containers for later disposal. Dispose in suitable
waste container.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully
resealed and kept upright to prevent leakage.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
1. Ammonium dimolybdate (CAS: 27546-07-2)
(Inhalation): 0.5mg/m3 (ACGIH)
2. SELENIOUS ACID (CAS: 7783-00-8)
(Inhalation): 0.2mg/m3 (ACGIH)
3. Sulfuric acid (<10%) (CAS: 7664-93-9 EC: 231-639-5)
(Inhalation): 0.2mg/m3 (ACGIH)
8.3 Individual protection measures, such as personal protective equipment (PPE)
Pictograms
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH
(US) or EN 166(EU).
Skin protection
Wear chemical resistant gloves and clothing.
Respiratory protection
NIOSH/MSHA approved air purifying respirator with an organic vapor cartidge or canister may be permissable
under certain circumstances where airborne concentrations are expected to exceed exposure limits.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Appearance/form (physical state, color, etc.) Blue Liquid
Odor Odorless
Odor threshold Not Available
pH 0-2.85
Melting point/freezing point 32 deg F
Initial boiling point and boiling range 212 deg F
Flash point Not Available
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Safety Data Sheet
Anodize Touch Up Solution
Evaporation rate 1
Flammability (solid, gas) Not Available
Upper/lower flammability limits Not Available
Vapor pressure 20
Vapor density Approx equal to water
Relative density 1.05-1.068
Solubility(ies) Soluble In Water
Partition coefficient: n-octanol/water Not Available
Auto-ignition temperature Not Available
Decomposition temperature Not Available
Viscosity Not Available
Explosive properties Not Available
Oxidizing properties Not Available
Other safety information
Does not contain VOC's
SECTION 10: Stability and reactivity
10.1 Reactivity
Not Reactive
10.2 Chemical stability
Stable
10.4 Conditions to avoid
Extreme Heat
10.5 Incompatible materials
Cyanides, organic solvents, strong reducing agents
SECTION 11: Toxicological information
Information on toxicological effects
Acute toxicity
The components of this material have been reviewed in various sources and the following selected endpoints are
published:
Water(7732-18-5)Oral LD50Rat>90 mL/kg
Copper(II) sulfate, pentahydrate (1:1:5)(7758-99-8)Oral LD50Rat960 mg/kgDermal LD50Rabbit1000 mg/kg (related
toSulfuric acid, copper(2+) salt (1:1))
Sulfuric acid(7664-93-9)Oral LD50Rat2140 mg/kgInhalation LC50Rat510 mg/m3 2 h
Carcinogenicity
Molybdate Diammonium: A3 - Confirmed animal with unknown relevance to Humans
SECTION 12: Ecological information
Toxicity
Copper(II) sulfate, pentahydrate (1:1:5)7758-99-8
Fish:LC50 96 h Lepomis macrochirus 0.66 -1.15 mg/L [semi-static];LC50 96 h
Lepomis macrochirus 0.96 -1.8 mg/L [static]; LC50 96 h
Oncorhynchus mykiss 0.1478 -0.165 mg/L [flow-through]; LC50 96 h
Oncorhynchus mykiss 0.09 -0.19 mg/L [static]; LC50 96 h
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Safety Data Sheet
Anodize Touch Up Solution
Pimephales promelas 0.6752 mg/L [static]
Invertebrate:EC50 48 h Daphnia magna0.147 -0.227 mg/L [static] EPA
Sulfuric acid7664-93-9
Fish:LC50 96 h Brachydanio rerio >500 mg/L [static]
SECTION 13: Disposal considerations
Disposal of the product
Consult appropriate federal and local regulations for disposal. Empty containers are subject to the same regulations.
SECTION 14: Transport information
DOT (US)
UN Number: UN1760
Class: 8
Packing Group: II
Proper Shipping Name: Corrosive Liquid, NOS (Sulfuric Acid, Selenious Acid)
Reportable quantity (RQ): 335 lbs
Small quantities may be shipped as Limited Quantities. Consult 49 CFR.
IMDG
UN Number:
Class:
Packing Group:
EMS Number:
Proper Shipping Name:
IATA
UN Number: UN1760
Class: 8
Packing Group: II
Proper Shipping Name: Corrosive Liquid, NOS (Sulfuric Acid, Selenious Acid)
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations specific for the product in question
Massachusetts Right To Know Components
Chemical name: Selenious acid
CAS number: 7783-00-8
New Jersey Right To Know Components
Common name: SELENOUS ACID
CAS number: 7783-00-8
Pennsylvania Right To Know Components
Chemical name: Selenous acid
CAS number: 7783-00-8
Massachusetts Right To Know Components
Chemical name: Copper
CAS number: 7440-50-8
New Jersey Right To Know Components
Common name: COPPER
CAS number: 7440-50-8
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Safety Data Sheet
Anodize Touch Up Solution
Pennsylvania Right To Know Components
Chemical name: Copper
CAS number: 7440-50-8
Massachusetts Right To Know Components
Chemical name: Sulfuric acid
CAS number: 7664-93-9
New Jersey Right To Know Components
Common name: SULFURIC ACID
CAS number: 7664-93-9
Pennsylvania Right To Know Components
Chemical name: Sulfuric acid
CAS number: 7664-93-9
California Prop. 65 components
Chemical name: Sulfuric acid (<10%)
CAS number: 7664-93-9
03/14/2003 - Cancer
Toxic Substances Control Act (TSCA) Inventory
Chemical name: Sulfuric acid
CAS number: 7664-93-9
HMIS Rating
Anodize Touch Up Solution
HEALTH *2
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION C
NFPA Rating
SECTION 16: Other information
16.1 Further information/disclaimer
DISCLAIMER: The information above is believed to be accurate and represents the best information currently
available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with
respect to such information, and we assume no liability resulting from its use. Users should make their own
investigation to determine the suitability of information for their particular purposes. In no event shall Caswell Inc be
liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental,
consequential or exemplary damages, whatsoever arising, even if Caswell Inc has been advised of the possibility of
such damages.
16.2 Preparation information
L CASWELL
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Safety Data Sheet
Anodize Touch Up Solution
Version: 1.0, Revision: 4, Supersedes: 3, Date of issue: 2015-07-16, p. 8 of 8