Casweld AL SDS

Casweld AL SDS

                                                 CASWELL INC
Safety Data Sheet
Casweld AL
SECTION 1: Identification

1.1   Product identifier

      Product name                          Casweld AL

      Product number                        CWAL
      Brand                                 Caswell

1.4   Supplier's details

      Name                                  Caswell Inc
      Address                               7696 Route 31
                                            Lyons, NY 14489
                                            USA

      Telephone                             315 946 1213
      Fax                                   315 946 4456
      email                                 sales@caswellplating.com

1.5   Emergency phone number(s)

                                            Office Hours (9-4ET): 315 946 1213
                                            24 Hour: CHEMTEL US# 1-800-255-3924          Intl# +01-813-248-0585

SECTION 2: Hazard identification

      General hazard statement
      Not considered a hazard in its solid form. Hazards are from fumes during use and heat.

2.1   Classification of the substance or mixture

      GHS classification in accordance with: (EC) No 1272/2008 (CLP)
      - Flammable solids (chapter 2.7), Cat. 2

2.2   GHS label elements, including precautionary statements

      Pictogram




      Signal word                           Warning


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      Hazard statement(s)
      H228                                  Flammable solid

      Precautionary statement(s)
      P210                                  Keep away from heat, hot surfaces, sparks, open flames, and other ignition
                                            sources. No smoking.
      P240                                  Ground/bond container and receiving equipment.
      P241                                  Use explosion-proof electrical/ventilating/lighting/…/equipment.
      P280                                  Wear protective gloves/protective clothing/eye protection/face protection.
      P370+P378                             In case of fire: Use … to extinguish.

SECTION 3: Composition/information on ingredients

3.1   Substances

      Hazardous components

      1. Aluminum (Wire)
      Concentration                         80 - 95 %
      EC no.                                231-072-3
      CAS no.                               7429-90-5
      Index no.                             013-002-00-1

      2. Silicon (metal)
      Concentration                         5 - 15 %
      CAS no.                               7440-21-3

SECTION 4: First-aid measures

4.1   Description of necessary first-aid measures

      General advice                        Consult a physician. Show this safety data sheet to the doctor in attendance.

      If inhaled                            If breathed in, move person into fresh air. If not breathing, give artificial
                                            respiration. Consult a physician.

      In case of skin contact               Wash off with soap and plenty of water. Get medical attention if symptoms
                                            occur.

      In case of eye contact                Rinse thoroughly with plenty of water for at least 15 minutes and consult a
                                            physician.

      If swallowed                          Do NOT induce vomiting. Never give anything by mouth to an unconscious
                                            person. Rinse mouth with water. Consult a physician.

      Personal protective equipment for first-aid responders
                                              See section 8

4.2   Most important symptoms/effects, acute and delayed
      not established

4.3   Indication of immediate medical attention and special treatment needed, if necessary
      not established

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SECTION 5: Fire-fighting measures

5.1   Suitable extinguishing media
      Use water spray, alcohol resistant foam, dry chemical or carbon dioxide. Welding sparks can ignite combusible and
      flammable materials. Use media recommended for burning material.

5.2   Specific hazards arising from the chemical
      Aluminum Oxides, Silicon Oxides

5.3   Special protective actions for fire-fighters
      Wear self-contained breathing apparatus for firefighting if necessary.

SECTION 6: Accidental release measures

6.1   Personal precautions, protective equipment and emergency procedures
      See section 8

6.2   Environmental precautions
      See section 13

6.3   Methods and materials for containment and cleaning up
      Pick up and arrange disposal without creating dust. Sweep up and shovel. Do not flush with water. Keep in
      suitable, closed containers for disposal.

SECTION 7: Handling and storage

7.1   Precautions for safe handling
      Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

7.2   Conditions for safe storage, including any incompatibilities
      Keep container tightly closed in a dry and well-ventilated place.

SECTION 8: Exposure controls/personal protection

8.1   Control parameters

      1. Silicon (CAS: 7440-21-3)
      PEL (Inhalation): See PNOR (Cal/OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      2. Silicon, Total dust (CAS: 7440-21-3)
      PEL (Inhalation): 15 mg/m3 (OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      3. Silicon, Total dust (CAS: 7440-21-3)
      PEL (Inhalation): 10 mg/m3, See PNOR (Cal/OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      4. Silicon, Total dust (CAS: 7440-21-3)
      REL (Inhalation): 10 mg/m3 (NIOSH)
      OSHA Annotated Table Z-1, www.osha.gov
      5. Silicon, Respirable fraction (CAS: 7440-21-3)
      PEL (Inhalation): 5 mg/m3 (OSHA)
      OSHA Annotated Table Z-1, www.osha.gov

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      6. Silicon, Respirable fraction (CAS: 7440-21-3)
      PEL (Inhalation): 5 mg/m3, See PNOR (Cal/OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      7. Silicon, Respirable fraction (CAS: 7440-21-3)
      REL (Inhalation): 5 mg/m3 (NIOSH)
      OSHA Annotated Table Z-1, www.osha.gov

8.2   Appropriate engineering controls
      Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

8.3   Individual protection measures, such as personal protective equipment (PPE)

      Pictograms




      Eye/face protection
      Welder's helmet or face shield with color absorbing lenses. Shield and filter to provide protection from UV radiation,
      infrared and molten metal approved to standard EN379. Filter shade to be a minimum of shade 9.

      Skin protection
      Heat resistant protective clothing. Safety boots, apron, arm and shoulder protection.

      Body protection
      Type A or B gloves. Type B recommended when high dexterity is required.

      Respiratory protection
      Use an air purifying dust respirator when welding or brazing in a confined space, or when local exhaust or
      ventialtion is not sufficient to keep exposure values within safe limits.

SECTION 9: Physical and chemical properties

      Information on basic physical and chemical properties

      Appearance/form (physical state, color, etc.)               Solid
      Odor                                                        None
      Odor threshold                                              Not Available
      pH                                                          Not Available
      Melting point/freezing point                                1080 deg F
      Initial boiling point and boiling range                     Not Available
      Flash point                                                 Not Available
      Evaporation rate                                            Not Available
      Flammability (solid, gas)                                   Not Available
      Upper/lower flammability limits                             Not Available
      Vapor pressure                                              Not Available
      Vapor density                                               Not Available
      Relative density                                            6 g/cm3
      Solubility(ies)                                             Insoluble
      Partition coefficient: n-octanol/water                      Not Available
      Auto-ignition temperature                                   Not Available
      Decomposition temperature                                   Not Available
      Viscosity                                                   Not Available

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      Explosive properties                                         Not Available
      Oxidizing properties                                         Not Available

SECTION 10: Stability and reactivity

10.1 Reactivity
     Contact with chemical substances like acids or strong bases cause generation of gas. Keep away from any
     possible contact with water, because of violent reaction and possible flash fire.

10.2 Chemical stability
     Stable

10.5 Incompatible materials
     Reacts with water and acid

10.6 Hazardous decomposition products
     When this product is used in a welding process, hazardous decomposition product would include those from
     volatilization, reaction or oxidation of the material listed in section 3 and those from the base metal and coating.
     The amount of fumes generated from this product varies with welding parameters and dimensions. Refer to
     applicable national exposure limits for fume compounds, including those exposure limits for fume compounds
     found in section 3. Reasonably expected gaseous products would include carbon oxides, nitrogen oxides and
     ozone. Air contaminants around the welding area can be affected by the welding process and influence the
     composition and quality of fumes and gases produced.

SECTION 11: Toxicological information

      Information on toxicological effects

      Acute toxicity
       Overexposure to welding fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness or
      irritation of the nose, throat or eyes. May cause sensitisation by skin contact.

      LD/LC50 Values that are relevant for classification
      Aluminum 7429-90-5 Oral LD50 >15900 mg/kg (rat) Inhalation LC50 >.888 mg/L/4 hr. (rat) LC50 12 mg/l (96h)
      (rainbow trout)

      Silicon 7440-21-3 Oral LD50 3160 mg/kg (rat)

      Respiratory or skin sensitization
      Overexposure to welding fumes may affect pulmonary function.

      Carcinogenicity
      Inhalation of welding fumes and gases can be dangerous to your health. Classification of welding fumes is difficult
      because of varying base materials, coatings, air contaminants and processes. The Internal Agency for Research
      on Cancer has classified welding fumes as possible carcinogenic to humans (Group 2B).

      STOT-repeated exposure
      Overexposure to welding fumes may affect pulmonary function.

SECTION 12: Ecological information

      Toxicity
      Welding rods contain metals which are considered to be very toxic towards aquatic organisms. Finely divided
      welding rods are therefore considered harmful to aquatic organisms

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     Bioaccumulative potential
     Welding rods contain heavy metals which bio accumulates in the food chain. The following figures are the bio
     concentration factor (BCF) for the substances on their own. BCF: Aluminum, BCF: 18

SECTION 13: Disposal considerations

     Disposal of the product
     Consult appropriate federal and local regulations for disposal. Empty containers are subject to the same
     regulations.

     Disposal of contaminated packaging
     Consult appropriate federal and local regulations for disposal. Empty containers are subject to the same
     regulations.

SECTION 14: Transport information

     DOT (US)
     Not dangerous goods

     IMDG
     Not dangerous goods

     IATA
     Not dangerous goods

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question
     Massachusetts Right To Know Components
     Chemical name: Aluminum (fume or dust)
     CAS number: 7429-90-5
     New Jersey Right To Know Components
     Common name: ALUMINUM
     CAS number: 7429-90-5
     Pennsylvania Right To Know Components
     Chemical name: Aluminum
     CAS number: 7429-90-5
     New Jersey Right To Know Components
     Common name: SILICON
     CAS number: 7440-21-3
     Pennsylvania Right To Know Components
     Chemical name: Silicon
     CAS number: 7440-21-3

     HMIS Rating

                   Casweld AL
       HEALTH                           1
       FLAMMABILITY                     1
       PHYSICAL HAZARD                  0

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        PERSONAL PROTECTION               D


      NFPA Rating




SECTION 16: Other information

16.1 Further information/disclaimer
     DISCLAIMER: The information above is believed to be accurate and represents the best information currently
     available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with
     respect to such information, and we assume no liability resulting from its use. Users should make their own
     investigation to determine the suitability of information for their particular purposes. In no event shall Caswell Inc be
     liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental,
     consequential or exemplary damages, whatsoever arising, even if Caswell Inc has been advised of the possibility
     of such damages.




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