COPPER CONDUCTIVE PAINT MSDS

COPPER CONDUCTIVE PAINT MSDS

                                                 CASWELL INC
Safety Data Sheet
Copper Conductive Paint
SECTION 1: Identification

1.1   Product identifier

      Product name                          Copper Conductive Paint

      Product number                        CCP
      Brand                                 Caswell

1.3   Recommended use of the chemical and restrictions on use
      Metallizing Paint

1.4   Supplier’s details

      Name                                  Caswell Inc
      Address                               117 Victor Heights Pkwy
                                            Victor, NY 14564
                                            USA

      Telephone                             315 946 1213
      Fax                                   315 946 4456
      email                                 sales@caswellplating.com

1.5   Emergency phone number(s)

                                            Office Hours (9-4ET): 315 946 1213
                                            24 Hour: CHEMTEL US# 1-800-255-3924           Intl# +01-813-248-0585

SECTION 2: Hazard identification

2.1   Classification of the substance or mixture
      - Carcinogenicity (chapter 3.6), Cat. 2
      - Skin corrosion/irritation (chapter 3.2), Cat. 2
      - Eye damage/irritation (chapter 3.3), Cat. 2
      - Hazardous to the aquatic environment - long-term hazard (chapter 4.1), Cat. 3

2.2   GHS label elements, including precautionary statements

      Pictogram




      Signal word                           Warning


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Safety Data Sheet
Copper Conductive Paint
      Hazard statement(s)
      H315                                Causes skin irritation
      H319                                Causes serious eye irritation
      H412                                Harmful to aquatic life with long lasting effects
      H351                                Suspected of causing cancer

      Precautionary statement(s)
      P264                                Wash … thoroughly after handling.
      P280                                Wear protective gloves/protective clothing/eye protection/face protection.
      P302+P352                           IF ON SKIN: Wash with plenty of water/...
      P321                                Specific treatment (see … on this label).
      P332+P313                           If skin irritation occurs: Get medical advice/attention.
      P362+P364                           Take off contaminated clothing and wash it before reuse.
      P305+P351+P338                      IF IN EYES: Rinse cautiously with water for several minutes. Remove
                                          contact lenses if present and easy to do. Continue rinsing.
      P337+P313                           If eye irritation persists: Get medical advice/attention.
      P273                                Avoid release to the environment.
      P501                                Dispose of contents/container to …
      P201                                Obtain special instructions before use.
      P202                                Do not handle until all safety precautions have been read and understood.
      P308+P313                           IF exposed or concerned: Get medical advice/attention.
      P405                                Store locked up.

2.3   Other hazards which do not result in classification

SECTION 3: Composition/information on ingredients

3.2   Mixtures


      Hazardous components

      1. WATER
      Concentration                       40 - 50 %

      Other names / synonyms              DIHYDROGEN OXIDE; h2o; HYDROGEN OXIDE; ICE; SNOW; STEAM;
                                          WATER, DISTILLED
      CAS no.                             7732-18-5


      2. Copper
      Concentration                       25 - 40 %
      CAS no.                             65357-62-2


      3. TITANIUM DIOXIDE
      Concentration                       5 - 10 %

      Other names / synonyms              1700 WHITE; A-FIL CREAM; ANATASE; ATLAS WHITE TITANIUM
                                          DIOXIDE; AUSTIOX; AUSTIOX R-CR 3; BAYERITIAN; BAYERTITAN;
                                          BAYERTITAN A; BAYERTITAN R-U-F; BAYTITAN; BROOKITE; C.I. 77891;
                                          C.I. PIGMENT WHITE 6; CAB-O-TI; CALCOTONE WHITE T; COSMETIC
                                          WHITE C47-5175; COSMETIC WHITE C47-9623; FLAMENCO;
                                          HOMBITAN; HOMBITAN R 101D; HOMBITAN R 610K; HORSE HEAD A-

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Safety Data Sheet
Copper Conductive Paint
                                             410; HORSE HEAD A-420; HORSE HEAD R-710; KH360; KRONOS;
                                             KRONOS 2073; KRONOS CL 220; KRONOS RN 40P; KRONOS RN 56;
                                             KRONOS TITANIUM DIOXIDE; LEVANOX WHITE RKB; NCI-CO4240;
                                             OCTAHEDRITE; P 25; P 25 (OXIDE); R 680; RAYOX; RO 2; RUNA ARH 20;
                                             RUNA ARH 200; RUNA RH20; RUTILE; RUTIOX CR; TI-PURE; TI-PURE R
                                             101; TI-PURE R 900; TI-PURE R 901; TI-PURE R 915; TIOFINE; TIONA
                                             T.D.; TIOXIDE; TIOXIDE AD-M; TIOXIDE R-CR; TIOXIDE R-SM; TIOXIDE
                                             R.XL; TIOXIDE RHD; TIOXIDE RSM; TIPAQUE; TIPAQUE R 820;
                                             TITAFRANCE; TITAN WHITE; TITANIA; TITANIC ACID ANHYDRIDE;
                                             TITANIC ANHYDRIDE; TITANIC OXIDE; TITANIUM OXIDE; Titanium oxide
                                             (TiO2); TITANIUM PEROXIDE; TITANIUM WHITE; TITANIUM(IV) OXIDE;
                                             TITANIUMDIOXIDE; TITANOX; TITANOX 2010; TITANOX RANC;
                                             TRIOXIDE(S); TRONOX; UNITANE; UNITANE O-110; UNITANE O-220;
                                             UNITANE OR 450; UNITANE OR 572; UNITANE OR 650; UNITANE OR-
                                             150; UNITANE OR-340; UNITANE OR-342; UNITANE OR-350; UNITANE
                                             OR-540; UNITANE OR-640; ZOPAQUE; ZOPAQUE LDC
    CAS no.                                  13463-67-7


    4. Silver
    Concentration                            1-5%

    Other names / synonyms                   ARGENTUM; C.I. 77870; L-3; SHELL SILVER; SILVER ATOM
    CAS no.                                  7440-22-4


    5. Carbon black (airborne, unbound particles of respirable size)
    Concentration                      1-5%

    Other names / synonyms                   acetylene black; Carbon Black; channel black; furnace black; lamp black;
                                             lampblack; Oil Black (Lampblack); thermal black
    CAS no.                                  1333-86-4


    6. N-METHYL-2-PYRROLIDONE
    Concentration                            1-5%

    Other names / synonyms                   1-METHYL-2-PYRROLIDINONE; 1-METHYL-5-PYRROLIDINONE; 2-
                                             Pyrrolidinone, 1-methyl-; METHYLPYRROLIDONE;
                                             METHYLPYRROLIDONE,N-,2-; N-METHYLPYRROLIDINONE; N-
                                             METHYLPYRROLIDONE; NMP
    EC no.                                   212-828-1
    CAS no.                                  872-50-4
    Index no.                                606-021-00-7

    - Eye damage/irritation (chapter 3.3), Cat. 2
    - Skin corrosion/irritation (chapter 3.2), Cat. 2

    H315                                     Causes skin irritation
    H319                                     Causes serious eye irritation


SECTION 4: First-aid measures


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Safety Data Sheet
Copper Conductive Paint
4.1   Description of necessary first-aid measures

      General advice                          Consult a physician. Show this safety data sheet to the doctor in attendance.

      If inhaled                              Do NOT induce vomiting. Never give anything by mouth to an unconscious
                                              person. Rinse mouth with water. Consult a physician.

      In case of skin contact                 Wash off with soap and plenty of water. Get medical attention if symptoms
                                              occur.

      In case of eye contact                  Rinse thoroughly with plenty of water for at least 15 minutes and consult a
                                              physician.

      If swallowed                            Do NOT induce vomiting. Never give anything by mouth to an unconscious
                                              person. Rinse mouth with water. Consult a physician.

      Personal protective equipment for first-aid responders
                                              Wear PPE per section 8

4.2   Most important symptoms/effects, acute and delayed
      Can cause moderate respiratory irritation, dizziness, weakness, fatique nausea and headaches. May cause metal
      fume, resulting in flu-like symptoms. Nasal perforation is possible from a single large or repeated smaller inhalation
      exposures. Suspect Cancer Hazard.

SECTION 5: Fire-fighting measures

5.1   Suitable extinguishing media
      Use extinguishing media appropriate for surrounding fire.

5.2   Specific hazards arising from the chemical
      May combust into CO2, CO and Nitrogen containing gasses.

5.3   Special protective actions for fire-fighters
      Wear self-contained breathing apparatus for firefighting if necessary.

SECTION 6: Accidental release measures

6.1   Personal precautions, protective equipment and emergency procedures
      Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at
      places where dust is formed. Keep away from sources of ignition - No smoking. For precautions see section 2.2.

6.2   Environmental precautions
      Should not be released into the environment.

6.3   Methods and materials for containment and cleaning up
      Use sand, kitty litter or absorbant cloth. Place in closed containers for disposal.

SECTION 7: Handling and storage

7.1   Precautions for safe handling
      Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

7.2   Conditions for safe storage, including any incompatibilities
      Keep container tightly closed in a dry and well-ventilated place.

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Copper Conductive Paint

SECTION 8: Exposure controls/personal protection

8.1   Control parameters

      1. Titanium dioxide - Total dust (CAS: 13463-67-7)
      PEL (Inhalation): 15 mg/m3 (OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      2. Titanium dioxide - Total dust (CAS: 13463-67-7)
      PEL (Inhalation): See PNOR (Cal/OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      3. Titanium dioxide - Total dust (CAS: 13463-67-7)
      REL (Inhalation): Ca, (ultrafine particles), 2.4 mg/m3Ȩfine), 0.3 mg/m3(ultrafine), See Appendix A, See Appendix C
      (NIOSH)
      OSHA Annotated Table Z-1, www.osha.gov
      4. SILVER (CAS: 7440-22-4 EC: 231-131-3)
      PEL-TWA (Inhalation): 0.01 mg/m3 (OSHA)
      USA. Occupational Exposure Limits
      (OSHA) - Table Z-1 Limits for Air
      Contaminants
      5. SILVER (CAS: 7440-22-4 EC: 231-131-4)
      PEL-TWA (Inhalation): 0.1 mg/m3 (ACGIH)
      USA. ACGIH Threshold Limit Values
      (TLV)
      6. Silver, metal and soluble compounds (as Ag) (CAS: 7440-22-4)
      PEL (Inhalation): 0.01 mg/m3 (OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      7. Silver, metal and soluble compounds (as Ag) (CAS: 7440-22-4)
      PEL (Inhalation): 0.01 mg/m3 (Cal/OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      8. Silver, metal and soluble compounds (as Ag) (CAS: 7440-22-4)
      REL (Inhalation): 0.01 mg/m3 (NIOSH)
      OSHA Annotated Table Z-1, www.osha.gov
      9. Carbon black (CAS: 1333-86-4)
      PEL (Inhalation): 3.5 mg/m3 (OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      10. Carbon black (CAS: 1333-86-4)
      PEL (Inhalation): 3.5 mg/m3 (Cal/OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      11. Carbon black (CAS: 1333-86-4)
      REL (Inhalation): 3.5 mg/m3Ȩwithout PAHs); when PAHs are present, NIOSH considers carbon black to be a
      potential occupational carcinogen., See Appendix A,ɓee Appendix C (NIOSH)
      OSHA Annotated Table Z-1, www.osha.gov

8.2   Appropriate engineering controls
      Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

8.3   Individual protection measures, such as personal protective equipment (PPE)

      Eye/face protection

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Safety Data Sheet
Copper Conductive Paint
     Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH
     (US) or EN 166(EU).

     Skin protection
     Wear chemical resistant gloves and clothing.

     Body protection
     Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the
     specific work-place., The type of protective equipment must be selected according to the concentration and amount
     of the dangerous substance at the specific workplace.

     Respiratory protection
     NIOSH/MSHA approved air purifying respirator with an organic vapor cartidge or canister may be permissable
     under certain circumstances where airborne concentrations are expected to exceed exposure limits.

SECTION 9: Physical and chemical properties

     Information on basic physical and chemical properties

     Appearance/form                                           Copper/Beige Colored Liquid
     Odor                                                      Slight
     Odor threshold
     pH
     Melting point/freezing point                              32 deg F
     Initial boiling point and boiling range                   212 deg F
     Flash point
     Evaporation rate                                          Slower than n-butyl Acetate
     Flammability (solid, gas)                                 None
     Upper/lower flammability limits
     Upper/lower explosive limits
     Vapor pressure
     Vapor density                                             Heavier Than Air
     Relative density                                          1.318
     Solubility(ies)                                           Partial In Water
     Partition coefficient: n-octanol/water
     Auto-ignition temperature
     Decomposition temperature
     Viscosity
     Explosive properties
     Oxidizing properties

     Other safety information
     VOC 0.30 lbs/Gl as packed

SECTION 10: Stability and reactivity

10.1 Reactivity
     Not Reactive

10.2 Chemical stability
     Stable

10.4 Conditions to avoid
     Sparks. Open Flame. Elevated Temperatures. Contamination

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Copper Conductive Paint

10.5 Incompatible materials
     Strong oxidizers, ammonia, peroxides, acids, chlorintated compounds

10.6 Hazardous decomposition products
     CO2, CO, Nitrogen

SECTION 11: Toxicological information

     Information on toxicological effects

     Acute toxicity
     Oral LD50: 3914 mg/kg (rat)
     Suspect Cancer Hazard

     Skin corrosion/irritation
     Possible Irritant

     Serious eye damage/irritation
     Possible Irritant

     Respiratory or skin sensitization
     Silver compounds are toxic if absorbed through skin. May cause system damage. The absorbtion of silver through
     breaks in the skin may result in local pigmentation.

     Carcinogenicity
     Suspect Cancer Hazard (IARC)

     STOT-repeated exposure
     Respiratory system, liver, kidneys, eyes, skin, bone marrow, cardiovascular system, lymphatic system

SECTION 12: Ecological information

     Toxicity
     Copper is a marine pollutant. Specific data on this mixture is not available. Avoid release into environment.

SECTION 13: Disposal considerations

     Disposal of the product
     SMALL SPILLS: Contain and absorb with absorbent material and place into containers for later disposal. Wash site
     of spillage thoroughly with water. LARGE SPILLS: Dike far ahead of spill to prevent further movement. Recover by
     pumping or by using a suitable absorbent material and place into containers for later disposal. Dispose in suitable
     waste container.

     Disposal of contaminated packaging
     Dispose of as unused product.

SECTION 14: Transport information
     DOT (US)
     Not dangerous goods

     IMDG

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Copper Conductive Paint
     Not dangerous goods

     IATA
     Not dangerous goods

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question

     Massachusetts Right To Know Components
     Chemical name: Copper
     CAS number: 65357-62-2

     New Jersey Right To Know Components
     Common name: TITANIUM DIOXIDE
     CAS number: 13463-67-7

     Pennsylvania Right To Know Components
     Chemical name: Titanium oxide
     CAS number: 13463-67-7

     Massachusetts Right To Know Components
     Chemical name: Silver
     CAS number: 7440-22-4

     New Jersey Right To Know Components
     Common name: SILVER
     CAS number: 7440-22-4

     Pennsylvania Right To Know Components
     Chemical name: Silver
     CAS number: 7440-22-4

     New Jersey Right To Know Components
     Common name: CARBON BLACK
     CAS number: 1333-86-4

     Pennsylvania Right To Know Components
     Chemical name: Carbon black
     CAS number: 1333-86-4

     California Prop. 65 components
     Chemical name: Carbon black (airborne, unbound particles of respirable size)
     CAS number: 1333-86-4
     02/21/2003 - cancer

     Massachusetts Right To Know Components
     Chemical name: N-Methyl-2-pyrrolidone
     CAS number: 872-50-4

     New Jersey Right To Know Components
     Common name: 1-METHYL-2-PYRROLIDONE
     CAS number: 872-50-4


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Safety Data Sheet
Copper Conductive Paint
      Pennsylvania Right To Know Components
      Chemical name: 2-Pyrrolidinone, 1-methyl- 2,beta-butoxyethoxyethyl Chloride
      CAS number: 872-50-4

      California Prop. 65 components
      Chemical name: N-METHYL-2-PYRROLIDONE
      CAS number: 872-50-4
      06/15/2001 - developmental

      HMIS Rating

              Copper Conductive Paint
        HEALTH                           *2
        FLAMMABILITY                      2
        PHYSICAL HAZARD                   0
        PERSONAL PROTECTION               H


      NFPA Rating




SECTION 16: Other information

16.1 Further information/disclaimer
     DISCLAIMER: The information above is believed to be accurate and represents the best information currently
     available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with
     respect to such information, and we assume no liability resulting from its use. Users should make their own
     investigation to determine the suitability of information for their particular purposes. In no event shall Caswell Inc be
     liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental,
     consequential or exemplary damages, whatsoever arising, even if Caswell Inc has been advised of the possibility of
     such damages.




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