Electroless Copper Part A SDS

Electroless Copper Part A SDS

                                                 CASWELL INC
Safety Data Sheet
Electroless Copper Part A

SECTION 1: Identification

1.1   Product identifier

      Product name                          Electroless Copper Part A

      Product number                        ELCUA
      Brand                                 Caswell

1.4   Supplier's details

      Name                                  Caswell Inc
      Address                               7696 Route 31
                                            Lyons, NY 14489
                                            USA

      Telephone                             315 946 1213
      Fax                                   315 946 4456
      email                                 sales@caswellplating.com

1.5   Emergency phone number(s)

                                            Office Hours (9-4ET): 315 946 1213
                                            24 Hour: CHEMTEL US# 1-800-255-3924           Intl# +01-813-248-0585


SECTION 2: Hazard identification

2.1   Classification of the substance or mixture

      GHS classification in accordance with: (US) OSHA (29 CFR 1910.1200)
      - Acute toxicity, oral (chapter 3.1), Cat. 4
      - Acute toxicity, inhalation (chapter 3.1), Cat. 4
      - Skin corrosion/irritation (chapter 3.2), Cat. 2
      - Eye damage/irritation (chapter 3.3), Cat. 2A
      - Hazardous to the aquatic environment - long-term hazard (chapter 4.1), Cat. 2

2.2   GHS label elements, including precautionary statements

      Pictogram




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Safety Data Sheet
Electroless Copper Part A




      Signal word                        Warning

      Hazard statement(s)
      H302                               Harmful if swallowed
      H332                               Harmful if inhaled
      H315                               Causes skin irritation
      H319                               Causes serious eye irritation
      H411                               Toxic to aquatic life with long lasting effects

      Precautionary statement(s)
      P264                               Wash … thoroughly after handling.
      P270                               Do not eat, drink or smoke when using this product.
      P301+P312                          IF SWALLOWED: Call a POISON CENTER/doctor/.../if you feel unwell,
      P330                               Rinse mouth.
      P501                               Dispose of contents/container to …
      P261                               Avoid breathing dust/fume/gas/mist/vapours/spray.
      P271                               Use only outdoors or in a well-ventilated area.
      P304+P340                          IF INHALED: Remove person to fresh air and keep comfortable for breathing.
      P312                               Call a POISON CENTER/doctor/... if you feel unwell.
      P280                               Wear protective gloves/protective clothing/eye protection/face protection.
      P302+P352                          IF ON SKIN: Wash with plenty of water/...
      P321                               Specific treatment (see … on this label).
      P332+P313                          If skin irritation occurs: Get medical advice/attention.
      P362+P364                          Take off contaminated clothing and wash it before reuse.
      P305+P351+P338                     IF IN EYES: Rinse cautiously with water for several minutes. Remove
                                         contact lenses if present and easy to do. Continue rinsing.
      P337+P313                          If eye irritation persists: Get medical advice/attention.
      P273                               Avoid release to the environment.
      P391                               Collect spillage.


SECTION 3: Composition/information on ingredients

3.1   Substances

      Hazardous components

      1. WATER
      Concentration                      > 75 %
      CAS no.                            7732-18-5

      2. TRIETHANOLAMINE
      Concentration                      5 - 10 %
      CAS no.                            102-71-6

      3. Ethylenediaminetetraacetic acid tetrasodium salt
      Concentration                       1-5%
      CAS no.                             64-02-8



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Electroless Copper Part A

      4. DIETHANOLAMINE
      Concentration                          1-5%
      EC no.                                 203-868-0
      CAS no.                                111-42-2
      Index no.                              603-071-00-1

      5. COPPER SULFATE PENTAHYDRATE
      Concentration              1-5%
      CAS no.                    7758-99-8

      6. Sodium hydroxide liquid
      Concentration                          Not specified
      EC no.                                 215-185-5
      CAS no.                                1310-73-2
      Index no.                              011-002-00-6


SECTION 4: First-aid measures

4.1   Description of necessary first-aid measures

      If inhaled                             If breathed in, move person into fresh air. If not breathing, give artificial
                                             respiration. Consult a physician.

      In case of skin contact                Take off contaminated clothing and shoes immediately. Wash off with soap
                                             and plenty of water. Consult a physician

      In case of eye contact                 Rinse thoroughly with plenty of water for at least 15 minutes and consult a
                                             physician.

      If swallowed                           Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical
                                             attention immediately if symptoms occur.

4.2   Most important symptoms/effects, acute and delayed
      Ingestion may be harmful or fatal. Symptoms include severe stomach and intestinal irritation, abdominal pain and
      vomiting of blood. Low blood pressure and shock may occur as a result of severe tissue damage.


SECTION 5: Fire-fighting measures

5.1   Suitable extinguishing media
      Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.3   Special protective actions for fire-fighters
      Wear self-contained breathing apparatus for firefighting if necessary.


SECTION 6: Accidental release measures

6.1   Personal precautions, protective equipment and emergency procedures
      Refer to section 8




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Electroless Copper Part A
6.2   Environmental precautions
      Do not allow to enter sewer or open water

6.3   Methods and materials for containment and cleaning up
      SMALL SPILLS: Contain and absorb with absorbent material and place into containers for later disposal. Wash site
      of spillage thoroughly with water. LARGE SPILLS: Dike far ahead of spill to prevent further movement. Recover by
      pumping or by using a suitable absorbent material and place into containers for later disposal. Dispose in suitable
      waste container.


SECTION 7: Handling and storage

7.1   Precautions for safe handling
      Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. For precautions see section 2.2.

7.2   Conditions for safe storage, including any incompatibilities
      Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully
      resealed and kept upright to prevent leakage.


SECTION 8: Exposure controls/personal protection

8.1   Control parameters

      1. Sodium hydroxide (CAS: 1310-73-2)
      PEL (Inhalation): 2 mg/m3 (OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      2. Sodium hydroxide (CAS: 1310-73-2)
      PEL (Inhalation): (C) 2 mg/m3 (Cal/OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      3. Sodium hydroxide (CAS: 1310-73-2)
      REL (Inhalation): (C) 2 mg/m3 (NIOSH)
      OSHA Annotated Table Z-1, www.osha.gov

8.3   Individual protection measures, such as personal protective equipment (PPE)

      Pictograms




      Eye/face protection
      Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH
      (US) or EN 166(EU).

      Skin protection
      Wear chemical resistant gloves and clothing.

      Body protection
      Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the




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Electroless Copper Part A
      specific work-place., The type of protective equipment must be selected according to the concentration and amount
      of the dangerous substance at the specific workplace.

      Respiratory protection
      NIOSH/MSHA approved air purifying respirator with an organic vapor cartidge or canister may be permissable
      under certain circumstances where airborne concentrations are expected to exceed exposure limits.


SECTION 9: Physical and chemical properties

      Information on basic physical and chemical properties

      Appearance/form (physical state, color, etc.)              Blue Liquid
      Odor                                                       Amine
      Odor threshold
      pH                                                         alakline
      Melting point/freezing point
      Initial boiling point and boiling range                    100 deg C
      Flash point                                                75 deg C CC
      Evaporation rate
      Flammability (solid, gas)                                  None
      Upper/lower flammability limits
      Vapor pressure
      Vapor density
      Relative density                                           1.1 g/cc
      Solubility(ies)                                            Miscible
      Partition coefficient: n-octanol/water
      Auto-ignition temperature                                  207 deg C
      Decomposition temperature
      Viscosity
      Explosive properties
      Oxidizing properties


SECTION 10: Stability and reactivity

10.2 Chemical stability
     Stable

10.4 Conditions to avoid
     Excess Heat, Flame

10.5 Incompatible materials
     Alkalis, ketones, organic anhydrides, organic halides, strong acids, aldehydes, strong oxidizers


SECTION 11: Toxicological information

      Information on toxicological effects

      Acute toxicity
      Triethanolamine:
      Oral LD50 Rat: 4.92 mL/kg



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Electroless Copper Part A
     Skin LD50 Rabbit: > 20 mL/kg
     Eye Irritation: Mild, 10 mg (Rabbit)
     Copper Sulfate:
     Oral LD50 Human: 1.088 mg(hydrate/kg)
     Oral LD50, Rat: 300mg/kg

     Skin corrosion/irritation
     Triethanolamine:
     Skin LD50 Rabbit: > 20 mL/kg

     Serious eye damage/irritation
     Triethanolamine:
     Eye Irritation: Mild, 10 mg (Rabbit)

     Germ cell mutagenicity
     Mutagenic effects have been observed on tests with human lymphocytes

     Carcinogenicity
     IARC-3: No


SECTION 12: Ecological information

     Toxicity
     Copper Sulfate is toxic to aquatic environments with long term effects.


SECTION 13: Disposal considerations

     Disposal of the product
     Consult appropriate federal and local regulations for disposal. Empty containers are subject to the same regulations.

     Disposal of contaminated packaging
     Consult appropriate federal and local regulations for disposal. Empty containers are subject to the same regulations.


SECTION 14: Transport information

     DOT (US)
     Not dangerous goods

     IMDG
     Not dangerous goods

     IATA
     Not dangerous goods


SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question
     New Jersey Right To Know Components




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Safety Data Sheet
Electroless Copper Part A
      Common name: TRIETHANOLAMINE
      CAS number: 102-71-6
      Pennsylvania Right To Know Components
      Chemical name: Ethanol, 2,2'-nitrilotris-
      CAS number: 102-71-6
      Massachusetts Right To Know Components
      Chemical name: Diethanolamine
      CAS number: 111-42-2
      New Jersey Right To Know Components
      Common name: DIETHANOLAMINE
      CAS number: 111-42-2
      Pennsylvania Right To Know Components
      Chemical name: Ethanol, 2,2'-iminobis-
      CAS number: 111-42-2
      Massachusetts Right To Know Components
      Chemical name: Sodium hydroxide
      CAS number: 1310-73-2
      New Jersey Right To Know Components
      Common name: SODIUM HYDROXIDE
      CAS number: 1310-73-2
      Pennsylvania Right To Know Components
      Chemical name: Sodium hydroxide
      CAS number: 1310-73-2

      HMIS Rating

             Electroless Copper Part A
        HEALTH                           1
        FLAMMABILITY                     2
        PHYSICAL HAZARD                  0
        PERSONAL PROTECTION              C


      NFPA Rating




SECTION 16: Other information

16.1 Further information/disclaimer
     DISCLAIMER: The information above is believed to be accurate and represents the best information currently
     available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with
     respect to such information, and we assume no liability resulting from its use. Users should make their own




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Safety Data Sheet
Electroless Copper Part A
    investigation to determine the suitability of information for their particular purposes. In no event shall Caswell Inc be
    liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental,
    consequential or exemplary damages, whatsoever arising, even if Caswell Inc has been advised of the possibility of
    such damages.




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