CASWELL INC
Safety Data Sheet
Electroless Copper Part B
SECTION 1: Identification
1.1 Product identifier
Product name Electroless Copper Part B
Product number ELCUB
Brand Caswell
1.4 Supplier's details
Name Caswell Inc
Address 7696 Route 31
Lyons, NY 14489
USA
Telephone 315 946 1213
Fax 315 946 4456
email sales@caswellplating.com
1.5 Emergency phone number(s)
Office Hours (9-4ET): 315 946 1213
24 Hour: CHEMTEL US# 1-800-255-3924 Intl# +01-813-248-0585
SECTION 2: Hazard identification
2.1 Classification of the substance or mixture
GHS classification in accordance with: (US) OSHA (29 CFR 1910.1200)
- Flammable liquids (chapter 2.6), Cat. 1
- Acute toxicity, oral (chapter 3.1), Cat. 1
- Acute toxicity, inhalation (chapter 3.1), Cat. 4
- Skin corrosion/irritation (chapter 3.2), Cat. 3
- Eye damage/irritation (chapter 3.3), Cat. 2
- Specific target organ toxicity, repeated exposure (chapter 3.9), Cat. 2
- Carcinogenicity (chapter 3.6), Cat. 1B
- Hazardous to the aquatic environment - acute hazard (chapter 4.1), Cat. 3
2.2 GHS label elements, including precautionary statements
Pictogram
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Safety Data Sheet
Electroless Copper Part B
Signal word Danger
Hazard statement(s)
H224 Extremely flammable liquid and vapor
H300 Fatal if swallowed
H332 Harmful if inhaled
H316 Causes mild skin irritation
H319 Causes serious eye irritation
H373 May cause damage to organs through prolonged or repeated exposure
H350 May cause cancer
H402 Harmful to aquatic life
Precautionary statement(s)
P210 Keep away from heat, hot surfaces, sparks, open flames, and other ignition
sources. No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P370+P378 In case of fire: Use … to extinguish.
P403+P235 Store in a well ventilated place. Keep cool.
P501 Dispose of contents/container to …
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/...
P321 Specific treatment (see … on this label).
P330 Rinse mouth.
P405 Store locked up.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 Call a POISON CENTER/doctor/... if you feel unwell.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P314 Get medical advice/attention if you feel unwell.
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P273 Avoid release to the environment.
SECTION 3: Composition/information on ingredients
3.2 Mixtures
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Safety Data Sheet
Electroless Copper Part B
Hazardous components
1. WATER
Concentration 71 %
CAS no. 7732-18-5
2. Methanol
Concentration 25 %
EC no. 200-659-6
CAS no. 67-56-1
Index no. 603-001-00-X
- Flammable liquids (chapter 2.6), Cat. 2
- Acute toxicity (chapter 3.1), Cat. 3
- Specific target organ toxicity, single exposure (chapter 3.8), Cat. 1
H225 Highly flammable liquid and vapor
H301 Toxic if swallowed
H311 Toxic in contact with skin
H331 Toxic if inhaled
H370 Causes damage to organs
3. Formaldehyde
Concentration 4%
EC no. 200-001-8
CAS no. 50-00-0
Index no. 605-001-00-5
- Carcinogenicity (chapter 3.6), Cat. 2
- Acute toxicity (chapter 3.1), Cat. 3
- Skin corrosion/irritation (chapter 3.2), Cat. 1B
- Sensitization, skin (chapter 3.4), Cat. 1
H301 Toxic if swallowed
H311 Toxic in contact with skin
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H331 Toxic if inhaled
H351 Suspected of causing cancer
SECTION 4: First-aid measures
4.1 Description of necessary first-aid measures
If inhaled If breathed in, move person into fresh air. If not breathing, give artificial
respiration. Consult a physician.
In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap
and plenty of water. Consult a physician
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Electroless Copper Part B
In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a
physician.
If swallowed Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical
attention immediately. Typical fatal dose is 100-125/ml
4.2 Most important symptoms/effects, acute and delayed
Victim may improve and then decline again up to 30 hours later.
SECTION 5: Fire-fighting measures
5.1 Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.3 Special protective actions for fire-fighters
Wear self-contained breathing apparatus for firefighting if necessary.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Refer to section 8
6.2 Environmental precautions
Do not allow to enter sewer or open water
6.3 Methods and materials for containment and cleaning up
Remove all ignition sources. SMALL SPILLS: Contain and absorb with absorbent material and place into containers
for later disposal. Wash site of spillage thoroughly with water. LARGE SPILLS: Dike far ahead of spill to prevent
further movement. Recover by pumping or by using a suitable absorbent material and place into containers for later
disposal. Dispose in suitable waste container.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully
resealed and kept upright to prevent leakage.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
1. METHYL ALCOHOL (CAS: 67-56-1 EC: 200-659-6)
PEL-TWA: 200 ppm (ACGIH)
2. METHYL ALCOHOL (CAS: 67-56-1 EC: 200-659-6)
Headache, Nausea, Dizziness, Eye damage Substances for which there is a Biological Exposure Index or Indices
(see BEI® section) Danger of cutaneous absorption
3. METHYL ALCOHOL (CAS: 67-56-1 EC: 200-659-6)
STEL: 250 ppm (ACGIH)
4. METHYL ALCOHOL (CAS: 67-56-1 EC: 200-659-6)
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Electroless Copper Part B
PEL-TWA: 200 ppm, 325 mg/m3 (NIOSH)
5. METHYL ALCOHOL (CAS: 67-56-1 EC: 200-659-6)
Potential for dermal absorption
6. METHYL ALCOHOL (CAS: 67-56-1 EC: 200-659-6)
PEL-TWA: 200 ppm, 260 mg/m3 (OSHA)
USA. Occupational Exposure Limits
(OSHA) - Table Z-1 Limits for Air
Contaminants
7. Methyl alcohol (CAS: 67-56-1)
PEL (Inhalation): 200 ppm (OSHA)
OSHA Annotated Table Z-1, www.osha.gov
8. Methyl alcohol (CAS: 67-56-1)
PEL (Inhalation): 260 mg/m3 (OSHA)
OSHA Annotated Table Z-1, www.osha.gov
9. Methyl alcohol (CAS: 67-56-1)
PEL (Inhalation): 200 ppm, (ST) 250 ppm, (C) 1000 ppm (Cal/OSHA)
OSHA Annotated Table Z-1, www.osha.gov
10. Methyl alcohol (CAS: 67-56-1)
REL (Inhalation): 200 ppm, (ST) 250 ppm (NIOSH)
OSHA Annotated Table Z-1, www.osha.gov
11. Formaldehyde (CAS: 50-00-0 EC: 200-001-8)
PEL-C (Inhalation): 0.3 ppm (ACGIH)
USA. ACGIH Threshold Limit Values (TLV)
12. Formaldehyde (CAS: 50-00-0 EC: 200-001-8)
Remarks: Upper Respiratory Tract irritation, Eye irritation, Suspected human carcinogen, Sensitizer
13. Formaldehyde (CAS: 50-00-0 EC: 200-001-8)
PEL-TWA (Inhalation): 0.016 ppm (NIOSH)
USA. NIOSH Recommended Exposure Limits
14. Formaldehyde (CAS: 500-00-0 EC: 200-001-8)
Potential Occupational Carcinogen
See Appendix A
15. Formaldehyde (CAS: 50-00-0 EC: 200-001-8)
PEL-C (Inhalation): 0.1 ppm (NIOSH)
USA. NIOSH Recommended Exposure Limits
16. Formaldehyde (CAS: 50-00-0 EC: 200-001-8)
1910.1048: This standard applies to all occupational exposures to formaldehyde, i.e. from formaldehyde gas, its
solutions, and materials that release formaldehyde OSHA specifically regulated carcinogen
17. Formaldehyde (CAS: 50-00-0 EC: 200-001-8)
0.75 ppm
OSHA Specifically Regulated Chemicals/Carcinogens
8.3 Individual protection measures, such as personal protective equipment (PPE)
Pictograms
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Safety Data Sheet
Electroless Copper Part B
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH
(US) or EN 166(EU).
Skin protection
Wear chemical resistant gloves and clothing.
Body protection
Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the
specific work-place., The type of protective equipment must be selected according to the concentration and amount
of the dangerous substance at the specific workplace.
Respiratory protection
NIOSH/MSHA approved air purifying respirator with an organic vapor cartidge or canister may be permissable
under certain circumstances where airborne concentrations are expected to exceed exposure limits.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Appearance/form (physical state, color, etc.) Colorless Liquid
Odor Pungent
Odor threshold
pH Not Available
Melting point/freezing point -98 deg C
Initial boiling point and boiling range 66 deg C
Flash point 12 deg C CC
Evaporation rate 5.9
Flammability (solid, gas) Flammable
Upper/lower flammability limits 6.0-36
Vapor pressure 97 at 25 deg C mm Hg
Vapor density 1.1
Relative density 1.05 g/cc
Solubility(ies) Miscible In Water
Partition coefficient: n-octanol/water
Auto-ignition temperature 464 deg C
Decomposition temperature
Viscosity
Explosive properties
Oxidizing properties
SECTION 10: Stability and reactivity
10.2 Chemical stability
Stable
10.4 Conditions to avoid
Excess Heat, Flame
10.5 Incompatible materials
String Oxidizing Agents. May react with metallic aluminum to form hydrogen gas.
SECTION 11: Toxicological information
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Electroless Copper Part B
Information on toxicological effects
Acute toxicity
Oral LD50 Woman: 36 mg/kg (formalin)
Carcinogenicity
Known Carcinogen
Summary of evaluation of the CMR properties
Formaldehyde is immediately dangerous to life or health. Acute exposure to vapors or mist at concentrations of 1
ppm cause membrane and respiratory tract irritation. Chronic exposure may promote the formation of squamous
cell nasal carcinomas and may cause cirrhosis of the live and chronic heart disease.
SECTION 12: Ecological information
Toxicity
Slighty toxic to aquatic life
SECTION 13: Disposal considerations
Disposal of the product
Consult appropriate federal and local regulations for disposal. Empty containers are subject to the same regulations.
Disposal of contaminated packaging
Consult appropriate federal and local regulations for disposal. Empty containers are subject to the same regulations.
SECTION 14: Transport information
DOT (US)
UN Number: UN1993
Class: 3
Packing Group: II
Proper Shipping Name: Flammable Liquids NOS (Methanol and Formaldehyde)
Reportable quantity (RQ):
Marine pollutant:
Poison inhalation hazard:
IMDG
UN Number: UN1993
Class: 3
Packing Group: II
EMS Number:
Proper Shipping Name: Flammable Liquids NOS (Methanol and Formaldehyde)
IATA
UN Number: UN1993
Class: 3
Packing Group: II
Proper Shipping Name: Flammable Liquids NOS (Methanol and Formaldehyde)
SECTION 15: Regulatory information
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Safety Data Sheet
Electroless Copper Part B
15.1 Safety, health and environmental regulations specific for the product in question
Massachusetts Right To Know Components
Chemical name: Methanol
CAS number: 67-56-1
New Jersey Right To Know Components
Common name: METHYL ALCOHOL
CAS number: 67-56-1
Pennsylvania Right To Know Components
Chemical name: Methanol
CAS number: 67-56-1
Massachusetts Right To Know Components
Chemical name: Formaldehyde
CAS number: 50-00-0
New Jersey Right To Know Components
Common name: FORMALDEHYDE
CAS number: 50-00-0
Pennsylvania Right To Know Components
Chemical name: Formaldehyde
CAS number: 50-00-0
California Prop. 65 components
Chemical name: Formaldehyde
CAS number: 50-00-0
01/01/1988 - cancer
HMIS Rating
Electroless Copper Part B
HEALTH *2
FLAMMABILITY 3
PHYSICAL HAZARD 0
PERSONAL PROTECTION C
NFPA Rating
SECTION 16: Other information
16.1 Further information/disclaimer
DISCLAIMER: The information above is believed to be accurate and represents the best information currently
available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with
respect to such information, and we assume no liability resulting from its use. Users should make their own
investigation to determine the suitability of information for their particular purposes. In no event shall Caswell Inc be
liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental,
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Electroless Copper Part B
consequential or exemplary damages, whatsoever arising, even if Caswell Inc has been advised of the possibility of
such damages.
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