Gold Tank SDS

Gold Tank SDS

                                                     CASWELL INC
Safety Data Sheet
Gold Tank Plating Solution
SECTION 1: Identification

1.1   Product identifier

      Product name                             Gold Tank Plating Solution

      Product number                           GLD
      Brand                                    Caswell

1.2   Other means of identification
      Blue liquid

1.3   Recommended use of the chemical and restrictions on use
      Gold Tank Plating Solution

1.4   Supplier’s details

      Name                                     Caswell Inc
      Address                                  7696 Route 31
                                               Lyons, NY 14489
                                               USA

      Telephone                                315 946 1213
      Fax                                      315 946 4456
      email                                    sales@caswellplating.com

1.5   Emergency phone number(s)

                                               Office Hours (9-4ET): 315 946 1213
                                               24 Hour: CHEMTEL US# 1-800-255-3924     Intl# +01-813-248-0585

SECTION 2: Hazard identification

2.1   Classification of the substance or mixture
      - Skin corrosion/irritation (chapter 3.2), Cat. 2
      - Eye damage/irritation (chapter 3.3), Cat. 2B
      - Acute toxicity, dermal (chapter 3.1), Cat. 4

2.2   GHS label elements, including precautionary statements

      Pictogram




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Safety Data Sheet
Gold Tank Plating Solution
      Signal word                         Warning

      Hazard statement(s)
      H315                                Causes skin irritation
      H320                                Causes eye irritation
      H312                                Harmful in contact with skin

      Precautionary statement(s)
      P264                                Wash … thoroughly after handling.
      P280                                Wear protective gloves/protective clothing/eye protection/face protection.
      P302+P352                           IF ON SKIN: Wash with plenty of water/...
      P321                                Specific treatment (see … on this label).
      P332+P313                           If skin irritation occurs: Get medical advice/attention.
      P362+P364                           Take off contaminated clothing and wash it before reuse.
      P305+P351+P338                      IF IN EYES: Rinse cautiously with water for several minutes. Remove
                                          contact lenses if present and easy to do. Continue rinsing.
      P337+P313                           If eye irritation persists: Get medical advice/attention.
      P312                                Call a POISON CENTER/doctor/... if you feel unwell.
      P501                                Dispose of contents/container to …

2.3   Other hazards which do not result in classification

SECTION 3: Composition/information on ingredients

3.2   Mixtures


      Hazardous components

      1. Component 1 (trade secret)
      Concentration                       1 - 5 % (Weight)

      - Xi: Irritating
      R36: Irritating to eyes.


      2. Component 2 (trade secret)
      Concentration                       1 - 5 % (Weight)


      3. Component 3 (trade secret)
      Concentration                       1 - 5 % (Weight)


      4. Component 4 (trade secret)
      Concentration                       1-5%

      - T+: Toxic
      R 60: May impair fertility.
      R61: May cause harm to the unborn child.
      (Rated only when above 8.5% in concentration)




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Safety Data Sheet
Gold Tank Plating Solution
      5. Aqueous solution, with components that are not hazardous or are below 1.0% in concentration (or below
      0.1% in concentration
for carcinogens, reproductive toxins, respiratory tract sensitizers, and mutagens). All ingredients are listed per
      the requirements
of regulations pertinent to Safety Data Sheet requirements under various regulations..
      Concentration                       Not specified
      CAS no.                             11111-11-1


      Trade secret statement (OSHA 1910.1200(i))
      The specific names and CAS #'s of components have been withheld as a trade secret.

SECTION 4: First-aid measures

4.1   Description of necessary first-aid measures

      General advice                        May be mildly irritating to eyes, throat and skin if directly exposed. No
                                            significant hazards to human health.

      If inhaled                            If breathed in, move person into fresh air. If not breathing, give artificial
                                            respiration.

      In case of skin contact               Wash off with soap and plenty of water.

      In case of eye contact                Flush eyes with water as a precaution.

      If swallowed                          Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical
                                            attention immediately if symptoms occur.

SECTION 5: Fire-fighting measures

5.1   Suitable extinguishing media
      Any

5.2   Specific hazards arising from the chemical
      None

SECTION 6: Accidental release measures

6.1   Personal precautions, protective equipment and emergency procedures
      Personnel who have received basic chemical safety
      training can generally handle small-scale releases (e.g., under 1 kg). For small releases, the minimum
      Personal Protective Equipment should be rubber gloves and rubber apron, splash goggles or safety
      glasses. Use caution during clean-up; avoid stepping into spilled solid or clean-up procedures that
      generate substantial amounts of dust.

6.2   Environmental precautions
      Avoid response actions that can cause a release of a significant amount of the substance (1 liter or more)
      into the environment.

6.3   Methods and materials for containment and cleaning up
      Any available



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Safety Data Sheet
Gold Tank Plating Solution
SECTION 7: Handling and storage

7.1   Precautions for safe handling
      HYGIENE PRACTICES: Keep out of reach of children. Follow good chemical hygiene practices. Do not
      smoke, drink, eat, or apply cosmetics in the chemical use area. Avoid inhalation of dusts. Use in wellventilated
      area. Avoid contact with skin or eyes. Remove contaminated clothing promptly. Clean up
      spilled product immediately.

7.2   Conditions for safe storage, including any incompatibilities
      Ensure all containers are correctly labeled. Store containers away
      from direct sunlight, sources of intense heat, or where freezing is possible. Store this product away from
      incompatible chemicals (See Section 10, Stability and Reactivity). Empty containers may contain residual
      material; therefore, empty containers should be handled with care. Material should be stored in
      secondary containers, or in a diked area, as appropriate. Storage and use areas should be covered
      with impervious materials. Inspect all

SECTION 8: Exposure controls/personal protection

8.1   Control parameters

      1. Component 4 (trade secret)
      TLV® (Oral): 2MG/M3 (ACGIH)

8.2   Appropriate engineering controls
      Use this product in well-ventilated environment. Safety showers, eye
      wash stations, and hand-washing equipment should be available.

8.3   Individual protection measures, such as personal protective equipment (PPE)

      Eye/face protection
      Splash goggles or safety glasses. If necessary, refer to U.S. OSHA 29 CFR
      1910.133, Canadian Standards, or the European Standard EN166.

      Skin protection
      Neoprene gloves or nitrile gloves should be used. Use triple gloves for spill
      response, as stated in Section 6 (Accidental Release Measures) of this SDS. If necessary, refer to U.S.
      OSHA 29 CFR 1910.138, appropriate Standards of Canada, or appropriate Standards of the European
      Economic Community.

      Body protection
      Use a body protection appropriate to task (e.g., lab coat, coveralls, or apron).
      Care should be taken to select protection for potentially exposed areas when prolonged exposure could
      occur in occupational settings.

      Respiratory protection
      None needed under normal conditions of use. Use NIOSH approved
      respirators if ventilation is inadequate to control sprays or mists. For situations in which significant
      amounts of sprays or mists could be generated, wear an air-purifying respirator with a high-efficiency
      particulate filter.

SECTION 9: Physical and chemical properties

      Information on basic physical and chemical properties


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Safety Data Sheet
Gold Tank Plating Solution
      Appearance/form                                           Blue Liquid
      Odor                                                      None
      Odor threshold
      pH                                                        5-8
      Melting point/freezing point                              32 deg F
      Initial boiling point and boiling range                   212 deg F
      Flash point                                               NA
      Evaporation rate                                          1
      Flammability (solid, gas)                                 Not Flammable
      Upper/lower flammability limits                           NA
      Upper/lower explosive limits                              NA
      Vapor pressure                                            NA
      Vapor density                                             1
      Relative density                                          1.23
      Solubility(ies)                                           Complete In Water
      Partition coefficient: n-octanol/water
      Auto-ignition temperature
      Decomposition temperature
      Viscosity
      Explosive properties
      Oxidizing properties

SECTION 10: Stability and reactivity

10.1 Reactivity
     Not reactive under typical conditions of use or handling; contact with water can generate some amount of
     heat.

10.2 Chemical stability
     Stable

10.3 Possibility of hazardous reactions
     This product is not self-reactive or air-reactive.
     This product can release heat upon contact with water.
     This product will not undergo hazardous polymerization.

10.5 Incompatible materials
     This product is not compatible with strong oxidizers, strong acids and water-reactive substances.

10.6 Hazardous decomposition products
     Products of thermal decomposition of this product can include carbon monoxide, carbon dioxide and
     compounds of sodium, nitrogen, sulfur.

SECTION 11: Toxicological information

      Information on toxicological effects

      Acute toxicity
      The following data are available for hazardous components in this product
      greater than 1% in concentration

      BORON COMPOUND
      Specific Locus Test-Drosophila melanogaster-Oral 714
      ppm

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Gold Tank Plating Solution
    Cytogenetic Analysis-Drosophila melanogaster-Oral
    714 ppm
    Oral-Rat TDLo: 37 g/kg (multi):Reproductive effects
    Oral-Infant LDLo :1000 mg/kg
    Oral-Man LDLo: 709 mg/kg
    Oral-Rat LD50: 2660 mg/kg
    Oral-Mouse LD50: 2000 mg/kg
    Intraperitoneal-Mouse LD50: 2711 mg/kg
    Intravenous-Mouse LD50: 1320 mg/kg
    Subcutaneous-Rabbit, adult LDLo:150 mg/kg
    Oral-Guinea Pig, adult LD50:5330 mg/kg

    GOLD SALT
    No data available.
    SULFITE COMPOUND
    DNA Inhibition-Human: lymphocyte 10 mmol/L
    Cytogenetic Analysis-Mouse: other cell types 25 mg/L
    Intravenous-Rat LD50: 115 mg/kg
    .
    SULFITE COMPOUND (continued)
    Intraperitoneal-Mouse LD50: 950 mg/kg
    Intravenous-Mouse LD50: 130 mg/kg
    Subcutaneous-Dog, adult LDLo: 1300 mg/kg "
    Subcutaneous-Cat, adult LDLo: 1300 mg/kg
    Intravenous-Cat, adult LDLo: 200 mg/kg
    Oral-Rabbit, adult LDLo: 2825 mg/kg
    Subcutaneous-Rabbit, adult LDLo: 300 mg/kg
    Intravenous-Rabbit, adult LD50: 65 mg/kg
    CHELATING AGENT
    Cytogenetic Analysis-Mouse-Intraperitoneal 50 mmol/L
    DNA Inhibition-Rabbit, adult: kidney 250 nmol/L
    Oral-Rat TDLo:7632 mg/kg (female 7-14D post): Teratogenic effects
    Oral-Rat TDLo: 7632 mg/kg (female 7-14D post): Reproductive
    effects
    Intraperitoneal-Rat LD50: 397 mg/kg
    Intraperitoneal-Mouse LD50: 250 mg/kg

    Skin corrosion/irritation
    Mild irritation may occur

    Serious eye damage/irritation
    Mild irritation may occur

    Respiratory or skin sensitization
    Mild irritation may occur

    Carcinogenicity
    Not a carcinogen

    Reproductive toxicity
    BORON COMPOUND: Animal feeding studies in rat, mouse and dog, at high doses, have demonstrated effects on
    fertility and testes. Studies with the chemically related boric acid in the rat, mouse and rabbit, at high doses,
    demonstrate developmental effects on the fetus, including fetal weight loss and minor skeletal variations. The doses
    administered were many times in excess of those to which humans would normally be exposed. Human

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Gold Tank Plating Solution
    epidemiological studies show no increase in pulmonary disease in occupational populations with chronic exposures
    to boric acid dust and sodium borate dust. A recent epidemiological study under the conditions of normal
    occupational exposure to borate dusts indicated no effect on fertility.

SECTION 12: Ecological information

    Toxicity
    Based on available data, this product may be harmful to contaminated terrestrial plants or animals.
    • Based on available data, this product may be harmful or fatal to contaminated aquatic plants or animals.
    • There are the following aquatic toxicity data available for components of this product that are over 1
    percent in concentration.

    BORON COMPOUND
    LC50 Fish (Carassium auratus, goldfish); 72 hours/178 mg/L
    LC50 Fish (Carassium auratus, goldfish); 72 hours/630mg/L
    LC50 Fish (Onchoryncus mykiss, rainbow trout); 24 days/ 150 mg/L
    EC50 (Daphnia magna); 48 hours, 1085-1402mg/L
    IC50 (Algae); 96 hours, 158 mg/L

    CHELATING AGENT
    EC50 Fish (catfish); 96 hours, 129ppm
    static test LC50 - Lepomis macrochirus (Bluegill sunfish) -
    41 mg/l - 96 hours
    static test EC50 - Daphnia magna (Water flea) - 625 mg/l
    - 48 hours

    Persistence and degradability
    When released into the soil, the components of this product are expected to biodegrade, dissipate in soils
    via oxidation, or otherwise chemically degrade or photo-decompose via solar radiation.

    Bioaccumulative potential
    The components of this product are not anticipated to bioaccumulate in any significant quantities. The
    following bioaccumulation data are available for components of this product.
    CHELATING AGENT: Lepomis macrochirus - 28 d - 80 μg/l; Bioconcentration factor (BCF): 1.8

SECTION 13: Disposal considerations

    Disposal of the product
    Consult appropriate federal and local regulations for disposal. Empty containers are subject to the same regulations.

SECTION 14: Transport information

    DOT (US)
    Not dangerous goods

    IMDG
    Not dangerous goods

    IATA
    Not dangerous goods

SECTION 15: Regulatory information


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Safety Data Sheet
Gold Tank Plating Solution
15.1 Safety, health and environmental regulations specific for the product in question

      SARA 311/312 Hazards
      ACUTE: YES, CHRONIC: YES, FIRE: NO, REACTIVE: NO

      Toxic Substances Control Act (TSCA) Inventory
      All components of this product are listed on the TCSA Inventory

      California Prop. 65 Components
      Nickel Chloride (less than 0.1%) is present in this solution and found on the Prop 65 List. WARNING: THIS
      PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER.

      HMIS Rating

             Gold Tank Plating Solution
        HEALTH                            1
        FLAMMABILITY                      0
        PHYSICAL HAZARD                   0
        PERSONAL PROTECTION               B


      NFPA Rating




SECTION 16: Other information

16.1 Further information/disclaimer
     DISCLAIMER: The information above is believed to be accurate and represents the best information currently
     available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with
     respect to such information, and we assume no liability resulting from its use. Users should make their own
     investigation to determine the suitability of information for their particular purposes. In no event shall Caswell Inc be
     liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental,
     consequential or exemplary damages, whatsoever arising, even if Caswell Inc has been advised of the possibility of
     such damages.




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