Gun Blue A327 SDS

Gun Blue A327 SDS

                                                                                CASWELL INC

Safety Data Sheet
Gun Blue A327
SECTION 1: Identification

1.1   Product identifier

      Product name                             Gun Blue A327

      Product number                           A327
      Brand                                    CASWELL

1.3   Recommended use of the chemical and restrictions on use
      Metal Antiquing Solution

1.4   Supplier's details

      Name                                     Caswell Inc
      Address                                  7696 Route 31
                                               Lyons, NY 14489
                                               USA

      Telephone                                315 946 1213
      Fax                                      315 946 4456
      email                                    sales@caswellplating.com

1.5   Emergency phone number(s)

                                               Office Hours (9-4ET): 315 946 1213
                                               24 Hour: CHEMTEL US# 1-800-255-3924     Intl# +01-813-248-0585

SECTION 2: Hazard identification

2.1   Classification of the substance or mixture
      - Skin corrosion/irritation (chapter 3.2), Cat. 1
      - Eye damage/irritation (chapter 3.3), Cat. 1

2.2   GHS label elements, including precautionary statements

      Pictogram




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Safety Data Sheet
Gun Blue A327
      Signal word                             Danger

      Hazard statement(s)
      H314                                    Causes severe skin burns and eye damage
      H318                                    Causes serious eye damage

      Precautionary statement(s)
      P264                                    Wash … thoroughly after handling.
      P270                                    Do not eat, drink or smoke when using this product.
      P301+P312                               IF SWALLOWED: Call a POISON CENTER/doctor/.../if you feel unwell,
      P330                                    Rinse mouth.
      P501                                    Dispose of contents/container to …
      P260                                    Do not breathe dust/fume/gas/mist/vapours/spray.
      P280                                    Wear protective gloves/protective clothing/eye protection/face protection.
      P301+P330+P331                          IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
      P303+P361+P353                          IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
                                              skin with water/shower.
      P363                                    Wash contaminated clothing before reuse.
      P304+P340                               IF INHALED: Remove person to fresh air and keep comfortable for breathing.
      P310                                    Immediately call a POISON CENTER/doctor/...
      P321                                    Specific treatment (see … on this label).
      P305+P351+P338                          IF IN EYES: Rinse cautiously with water for several minutes. Remove
                                              contact lenses if present and easy to do. Continue rinsing.
      P405                                    Store locked up.
      P273                                    Avoid release to the environment.
      P391                                    Collect spillage.

SECTION 3: Composition/information on ingredients

3.2   Mixtures

      Hazardous components

      1. WATER
      Concentration                           90 - 98 %
      CAS no.                                 7732-18-5


      2. HYDROCHLORIC ACID (<37%)
      Concentration                           1-4%
      EC no.                                  231-595-7
      CAS no.                                 7647-01-0
      Index no.                               017-002-01-X

      - Skin corrosion/irritation (chapter 3.2), Cat. 1B
      - Specific target organ toxicity, single exposure (chapter 3.8), Cat. 3

      H314                                    Causes severe skin burns and eye damage
      H335                                    May cause respiratory irritation


      3. Tellurium oxide
      Concentration                           0.01 - 0.05 %
      CAS no.                                 7446-07-3
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Safety Data Sheet
Gun Blue A327


      4. Surfactants, defoamers, plasticizers
      Concentration                        0.005 - 0.01 %


SECTION 4: First-aid measures

4.1   Description of necessary first-aid measures

      General advice                           Avoid all contact. Corrosive to skin, eyes and mucous membranes.

      If inhaled                               If breathed in, move person into fresh air. If not breathing, give artificial
                                               respiration. Consult a physician.

      In case of skin contact                  Wash off with soap and plenty of water. Consult a physician.

      In case of eye contact                   Rinse thoroughly with plenty of water for at least 15 minutes and consult a
                                               physician.

      If swallowed                             Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical
                                               attention immediately if symptoms occur.

4.2   Most important symptoms/effects, acute and delayed
      Ingestion will result in metallic taste, garlic breath and nausea.

SECTION 5: Fire-fighting measures

5.1   Suitable extinguishing media
      Dry chemical, foam, carbon dioxide, water fog.

5.3   Special protective actions for fire-fighters
      Wear self-contained breathing apparatus for firefighting if necessary.

SECTION 6: Accidental release measures

6.1   Personal precautions, protective equipment and emergency procedures
      Ensure adequate ventilation. Use personal protective equipment. For personal protection see section 8.

6.3   Methods and materials for containment and cleaning up
      SMALL SPILLS: Contain and absorb with absorbent material and place into containers for later disposal. Wash site
      of spillage thoroughly with water. LARGE SPILLS: Dike far ahead of spill to prevent further movement. Recover by
      pumping or by using a suitable absorbent material and place into containers for later disposal. Dispose in suitable
      waste container.

SECTION 7: Handling and storage

7.1   Precautions for safe handling
      Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully
      resealed and kept upright to prevent leakage.

SECTION 8: Exposure controls/personal protection


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Safety Data Sheet
Gun Blue A327
8.1   Control parameters

      1. Hydrogen chloride (CAS: 7647-01-0)
      PEL (Inhalation): (C) 5 ppm (OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      2. Hydrogen chloride (CAS: 7647-01-0)
      PEL (Inhalation): (C) 7 mg/m3 (OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      3. Hydrogen chloride (CAS: 7647-01-0)
      PEL (Inhalation): (C) 5 ppm (Cal/OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      4. Hydrogen chloride (CAS: 7647-01-0)
      REL (Inhalation): (C) 5 ppm (NIOSH)
      OSHA Annotated Table Z-1, www.osha.gov

8.3   Individual protection measures, such as personal protective equipment (PPE)

      Pictograms




      Eye/face protection
      Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH
      (US) or EN 166(EU).

      Skin protection
      Wear chemical resistant gloves and clothing.

      Body protection
      Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the
      specific work-place., The type of protective equipment must be selected according to the concentration and amount
      of the dangerous substance at the specific workplace.

      Respiratory protection
      NIOSH/MSHA approved air purifying respirator with an organic vapor cartidge or canister may be permissable
      under certain circumstances where airborne concentrations are expected to exceed exposure limits.

SECTION 9: Physical and chemical properties

      Information on basic physical and chemical properties

      Appearance/form (physical state, color, etc.)              Clear To Light Yellow Solution
      Odor                                                       Mild Acidic
      Odor threshold
      pH                                                         0-1
      Melting point/freezing point                               None/32 deg F
      Initial boiling point and boiling range                    215 deg F
      Flash point                                                None
      Evaporation rate                                           Approx equal to water
      Flammability (solid, gas)                                  None
      Upper/lower flammability limits


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Safety Data Sheet
Gun Blue A327
      Vapor pressure
      Vapor density                                              Approx equal to water
      Relative density                                           1.005-1.025
      Solubility(ies)                                            Complete in water
      Partition coefficient: n-octanol/water
      Auto-ignition temperature
      Decomposition temperature
      Viscosity
      Explosive properties
      Oxidizing properties                                       VOC=0

SECTION 10: Stability and reactivity

10.1 Reactivity
     Will not occur

10.2 Chemical stability
     This is a stable material

10.4 Conditions to avoid
     Avoid extreme heat

10.5 Incompatible materials
     May react with strong acids. May react with strong reducing agents. Flammable and combustible materials

10.6 Hazardous decomposition products
     None Known

SECTION 11: Toxicological information

      Information on toxicological effects

      Acute toxicity
      Not Known

      Germ cell mutagenicity
      Not Available

      STOT-single exposure
      Not Available

SECTION 12: Ecological information

      Toxicity
      Not Available

SECTION 13: Disposal considerations

      Disposal of the product
      Waste must be handled in accordance with all federal, state, provincial, and local regulations. Transport waste
      material to an authorized waste location, or incinerate under controlled conditions.

      Selenous acid (7783-00-8)


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Safety Data Sheet
Gun Blue A327
     RCRA: waste number U204

     Disposal of contaminated packaging
     Consult appropriate federal and local regulations for disposal. Empty containers are subject to the same regulations.

SECTION 14: Transport information

     DOT (US)
     UN Number: UN1789
     Class: 8
     Packing Group: II
     Proper Shipping Name: Hydrochloric Acid Solution
     Reportable quantity (RQ):
     Marine pollutant:
     Poison inhalation hazard:
     Quantities under 1L may be shipped as LTD QTY within the USA by Ground.

     IMDG
     UN Number: UN1789
     Class: 8
     Packing Group: II
     EMS Number:
     Proper Shipping Name: Hydrochloric Acid Solution

     IATA
     UN Number: UN1789
     Class: 8
     Packing Group: II
     Proper Shipping Name: Hydrochloric Acid Solution

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question
     Massachusetts Right To Know Components
     Chemical name: Hydrochloric acid
     CAS number: 7647-01-0
     New Jersey Right To Know Components
     Common name: HYDROGEN CHLORIDE
     CAS number: 7647-01-0
     Pennsylvania Right To Know Components
     Chemical name: Hydrochloric acid
     CAS number: 7647-01-0

     HMIS Rating

                  Gun Blue A327
       HEALTH                           2
       FLAMMABILITY                     0
       PHYSICAL HAZARD                  0
       PERSONAL PROTECTION              C




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Safety Data Sheet
Gun Blue A327
      NFPA Rating




SECTION 16: Other information

16.1 Further information/disclaimer
     DISCLAIMER: The information above is believed to be accurate and represents the best information currently
     available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with
     respect to such information, and we assume no liability resulting from its use. Users should make their own
     investigation to determine the suitability of information for their particular purposes. In no event shall Caswell Inc be
     liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental,
     consequential or exemplary damages, whatsoever arising, even if Caswell Inc has been advised of the possibility of
     such damages.




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