Mega Black SDS

Mega Black SDS

                                                                                        CASWELL INC

Safety Data Sheet
Caswell Mega Black
SECTION 1: Identification

1.1   Product identifier

      Product name                         Caswell Mega Black

      Product number                       CMB
      Brand                                CASWELL

1.2   Other means of identification
      Blue liquid

1.3   Recommended use of the chemical and restrictions on use
      Metal Blackening of Steel & Iron

1.4   Supplier's details

      Name                                 Caswell Inc
      Address                              7696 Route 31
                                           Lyons NY 14489
                                           USA

      Telephone                            315 946 1213
      Fax                                  315 946 4456
      email                                sales@caswellplating.com

1.5   Emergency phone number(s)

                                           Office Hours (9-4ET): 315 946 1213
                                           24 Hour: CHEMTEL US# 1-800-255-3924                 Intl# +01-813-248-0585

SECTION 2: Hazard identification

2.1   Classification of the substance or mixture

      - Acute hazards to the aquatic environment (chapter 4.1), Cat. 1
      - Long-term hazards to the aquatic environment (chapter 4.1), Cat. 1

2.2   GHS label elements, including precautionary statements

      Pictogram


                                                          Version: 1.0, Revision: 4, Supersedes: 3, Date of issue: 2015-07-16, p. 1 of 6
Safety Data Sheet
Caswell Mega Black




      Signal word                           Warning

      Hazard statement(s)
      H400                                  Very toxic to aquatic life
      H410                                  Very toxic to aquatic life with long lasting effects

      Precautionary statement(s)
      P273                                  Avoid release to the environment.
      P391                                  Collect spillage.
      P501                                  Dispose of contents/container to …

SECTION 3: Composition/information on ingredients

3.2   Mixtures

      Hazardous components

      1. WATER OR OTHER NON-REPORTABLE INGREDIENTS
      Concentration               80 - 100 % (weight)
      CAS no.                     7732-18-5


      2. SELENIOUS ACID
      Concentration                         1 - < 2 % (weight)
      CAS no.                               7783-00-8


      3. Copper (II) sulfate
      Concentration                         0.1 - 1 % (weight)
      EC no.                                231-847-6
      CAS no.                               7758-98-7
      Index no.                             029-004-00-0

      - Acute toxicity (chapter 3.1), Cat. 4
      - Serious eye damage/eye irritation (chapter 3.3), Cat. 2
      - Skin corrosion/irritation (chapter 3.2), Cat. 2
      - Hazardous to the aquatic environment, short-term (acute) (chapter 4.1), Cat. 1
      - Hazardous to the aquatic environment, long-term (chronic) (chapter 4.1), Cat. 1

      H302                                  Harmful if swallowed
      H315                                  Causes skin irritation
      H319                                  Causes serious eye irritation
      H400                                  Very toxic to aquatic life
      H410                                  Very toxic to aquatic life with long lasting effects


      4. Ethylenediaminetetraacetic acid tetrasodium salt
      Concentration                       0.1 - 0.2 % (weight)
      CAS no.                             64-02-8

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Safety Data Sheet
Caswell Mega Black


SECTION 4: First-aid measures

4.1   Description of necessary first-aid measures

      If inhaled                            If breathed in, move person into fresh air. If not breathing, give artificial
                                            respiration. Consult a physician.

      In case of skin contact               Wash off with soap and plenty of water. Consult a physician.

      In case of eye contact                Rinse thoroughly with plenty of water for at least 15 minutes and consult a
                                            physician.

      If swallowed                          Do NOT induce vomiting. Never give anything by mouth to an unconscious
                                            person. Rinse mouth with water. Consult a physician.

SECTION 5: Fire-fighting measures

5.1   Suitable extinguishing media
      Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2   Specific hazards arising from the chemical
      May produce toxic selenious fumes. Reactions with organics and strong reducing agents can produce volatile
      organoselenides or hydrogen selenide.

SECTION 6: Accidental release measures

6.1   Personal precautions, protective equipment and emergency procedures
      SMALL SPILLS: Contain and absorb with absorbent material and place into containers for later disposal. Wash site
      of spillage thoroughly with water. LARGE SPILLS: Dike far ahead of spill to prevent further movement. Recover by
      pumping or by using a suitable absorbent material and place into containers for later disposal. Dispose in suitable
      waste container.

SECTION 7: Handling and storage

7.1   Precautions for safe handling
      Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully
      resealed and kept upright to prevent leakage.

SECTION 8: Exposure controls/personal protection

8.3   Individual protection measures, such as personal protective equipment (PPE)

      Pictograms




      Eye/face protection
      Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH
      (US) or EN 166(EU).


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Safety Data Sheet
Caswell Mega Black
     Skin protection
     Wear chemical resistant gloves and clothing.

     Respiratory protection
     NIOSH/MSHA approved air purifying respirator with an organic vapor cartidge or canister may be permissable
     under certain circumstances where airborne concentrations are expected to exceed exposure limits.

SECTION 9: Physical and chemical properties

     Information on basic physical and chemical properties

     Appearance/form (physical state, color, etc.)              Blue Liquid
     Odor                                                       Characteristic
     Odor threshold
     pH                                                         2.1-2.7
     Melting point/freezing point
     Initial boiling point and boiling range                    218 deg F
     Flash point
     Evaporation rate                                           1
     Flammability (solid, gas)
     Upper/lower flammability limits
     Vapor pressure                                             20
     Vapor density                                              Approx equal to water
     Relative density                                           1.05-1.075
     Solubility(ies)                                            Soluble In Water
     Partition coefficient: n-octanol/water
     Auto-ignition temperature
     Decomposition temperature
     Viscosity
     Explosive properties
     Oxidizing properties

SECTION 10: Stability and reactivity

10.2 Chemical stability
     Stable

10.5 Incompatible materials
     Cyanides, organic solvents, strong reducing agents

SECTION 11: Toxicological information

     Information on toxicological effects

     Acute toxicity
     Not Available

SECTION 12: Ecological information

     Toxicity
     Harmful to aquatic environment

SECTION 13: Disposal considerations

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Safety Data Sheet
Caswell Mega Black

     Disposal of the product
     Consult appropriate federal and local regulations for disposal. Empty containers are subject to the same regulations.

SECTION 14: Transport information

     DOT (US)
     Not dangerous goods

     IMDG
     Not dangerous goods

     IATA
     Not dangerous goods

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question
     Massachusetts Right To Know Components
     Chemical name: Selenious acid
     CAS number: 7783-00-8
     New Jersey Right To Know Components
     Common name: SELENOUS ACID
     CAS number: 7783-00-8
     Pennsylvania Right To Know Components
     Chemical name: Selenous acid
     CAS number: 7783-00-8
     Massachusetts Right To Know Components
     Chemical name: Copper
     CAS number: 7440-50-8
     New Jersey Right To Know Components
     Common name: COPPER
     CAS number: 7440-50-8
     Pennsylvania Right To Know Components
     Chemical name: Copper
     CAS number: 7440-50-8
     Massachusetts Right To Know Components
     Chemical name: Cupric sulfate
     CAS number: 7758-98-7
     New Jersey Right To Know Components
     Common name: CUPRIC SULFATE
     CAS number: 7758-98-7
     Pennsylvania Right To Know Components
     Chemical name: Sulfuric acid copper(2+) salt (1:1)
     CAS number: 7758-98-7

     HMIS Rating

               Caswell Mega Black


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Safety Data Sheet
Caswell Mega Black
        HEALTH                           *2
        FLAMMABILITY                      0
        PHYSICAL HAZARD                   0
        PERSONAL PROTECTION               C


      NFPA Rating




SECTION 16: Other information

16.1 Further information/disclaimer
     DISCLAIMER: The information above is believed to be accurate and represents the best information currently
     available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with
     respect to such information, and we assume no liability resulting from its use. Users should make their own
     investigation to determine the suitability of information for their particular purposes. In no event shall Caswell Inc be
     liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental,
     consequential or exemplary damages, whatsoever arising, even if Caswell Inc has been advised of the possibility of
     such damages.

16.2 Preparation information
     L CASWELL




                                                             Version: 1.0, Revision: 4, Supersedes: 3, Date of issue: 2015-07-16, p. 6 of 6