Nickel Anode SDS

Nickel Anode SDS

                                                                               CASWELL INC

Safety Data Sheet
Nickel Anode
SECTION 1: Identification

1.1   Product identifier

      Product name                           Nickel Anode

      Product number                         NKANOD
      Brand                                  Caswell

1.4   Supplier's details

      Name                                   Caswell Inc
      Address                                7696 Route 31
                                             Lyons NY 14489
                                             USA

      Telephone                              315 946 1213
      Fax                                    315 946 4456
      email                                  sales@caswellplating.com

1.5   Emergency phone number(s)

                                             Office Hours (9-4ET): 315 946 1213
                                             24 Hour: CHEMTEL US# 1-800-255-3924      Intl# +01-813-248-0585

SECTION 2: Hazard identification

2.1   Classification of the substance or mixture

      GHS classification in accordance with: OSHA (29 CFR 1910.1200)

      - Sensitization, skin (C.4.7), Cat. 1
      - Carcinogenicity (C.4.9), Cat. 2
      - Specific target organ toxicity (repeated exposure) (C.4.12), Cat. 1

2.2   GHS label elements, including precautionary statements

      Pictogram




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Safety Data Sheet
Nickel Anode




      Signal word                             Danger

      Hazard statement(s)
      H317                                    May cause an allergic skin reaction
      H351                                    Suspected of causing cancer [route]
      H372                                    Causes damage to organs [organs] through prolonged or repeated exposure
                                              [route]

      Precautionary statement(s)
      P261                                    Avoid breathing dust/fume/gas/mist/vapors/spray.
      P272                                    Contaminated work clothing must not be allowed out of the workplace.
      P280                                    Wear protective gloves/protective clothing/eye protection/face protection.
      P302+P352                               IF ON SKIN: Wash with plenty of water/...
      P333+P313                               If skin irritation or rash occurs: Get medical advice/attention.
      P321                                    Specific treatment (see … on this label).
      P363                                    Wash contaminated clothing before reuse.
      P501                                    Dispose of contents/container to …
      P201                                    Obtain special instructions before use.
      P202                                    Do not handle until all safety precautions have been read and understood.
      P308+P313                               IF exposed or concerned: Get medical advice/attention.
      P405                                    Store locked up.
      P260                                    Do not breathe dust/fume/gas/mist/vapors/spray.
      P264                                    Wash … thoroughly after handling.
      P270                                    Do not eat, drink or smoke when using this product.
      P314                                    Get medical advice/attention if you feel unwell.

SECTION 3: Composition/information on ingredients

3.2   Mixtures

      Hazardous components

      1. NICKEL POWDER
      Concentration                           Not specified
      EC no.                                  231-111-4
      CAS no.                                 7440-02-0
      Index no.                               028-002-00-7

      - Carcinogenicity (C.4.9), Cat. 2
      - Sensitization, skin (C.4.7), Cat. 1

      H317                                    May cause an allergic skin reaction
      H351                                    Suspected of causing cancer [route]


SECTION 4: First-aid measures




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Safety Data Sheet
Nickel Anode
4.1   Description of necessary first-aid measures

      General advice                         Under normal handling and use, exposure to solid forms of this material
                                             present few health haz-ards. Subsequent operations such as grinding,
                                             melting or welding may produce hazardous dust or fumes which can be
                                             inhaled or come in contact with the skin or eyes. Emergency responders
                                             should take care to avoid secondary exposure to nickel particulate. Wear
                                             appropriate protective equipment.

      If inhaled                             In case of accident by inhalation: remove casualty to fresh air and keep at
                                             rest.

      In case of skin contact                After contact with skin, wash immediately with plenty of water

      In case of eye contact                 Flush eyes with lukewarm water, including under upper and lower eyelids, for
                                             at least 15 minutes. Seek medical attention.

      If swallowed                           If swallowed, do not induce vomiting: seek medical advice immediately and
                                             show this container or label.

SECTION 5: Fire-fighting measures

5.1   Suitable extinguishing media
      Use media suitable to extinguish surrounding fire.

5.2   Specific hazards arising from the chemical
      This product does not present fire or explosion hazards as shipped. Fine dust from processing may ignite if allowed
      to accumulate and subjected to an ignition source. When heated to high temperatures, nickel oxide may be
      produced, keep containers cool with water spray.

5.3   Special protective actions for fire-fighters
      Full face, self-contained breathing apparatus and full protective clothing when necessary.

SECTION 6: Accidental release measures

6.1   Personal precautions, protective equipment and emergency procedures
      Wear appropriate respiratory and protective equipment specified in section 8. Avoid creating dusts. Avoid breathing
      dust or fume. Isolate spill area and provide ventilation.

6.2   Environmental precautions
      Do not allow to enter drains or to be released to the environment.

6.3   Methods and materials for containment and cleaning up
      For larger pieces - pick up mechanically. For chips or dust - vacuum spill using a system equipped with a HEPA
      filtration system and place in properly labeled closed containers. Special precautions must be taken when changing
      filters on HEPA vacuum cleaners used to clean up hazardous materials. Caution should be taken to minimize
      airborne generation of particulate and avoid contamination of air and water.

SECTION 7: Handling and storage

7.1   Precautions for safe handling




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Safety Data Sheet
Nickel Anode
      Handle in a well-ventilated area. Avoid creating dust. Avoid exposure to high temperature. Avoid breathing dust or
      fumes. Avoid contact with skin and eyes. Wash thoroughly before eating or smoking. See section 8 for infor-mation
      on personal protection equipment.

7.2   Conditions for safe storage, including any incompatibilities
      Store in a sealed container. Store in a cool, dry area. See sec-tion 10 for more information on incompatible materials

SECTION 8: Exposure controls/personal protection

8.1   Control parameters

      1. Nickel, metal and insoluble compounds (as Ni) (CAS: 7440-02-0)
      PEL (Inhalation): 1 mg/m3 (OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      PEL (Inhalation): metal 0.5 mg/m3, insoluble 0.1 mg/m3 (Cal/OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      REL (Inhalation): Ca, 0.015 mg/m3, See Appendix A (NIOSH)
      OSHA Annotated Table Z-1, www.osha.gov
      2. Nickel, soluble compounds (as Ni) (CAS: 7440-02-0)
      PEL (Inhalation): 1 mg/m3 (OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      PEL (Inhalation): 0.05 mg/m3 (Cal/OSHA)
      OSHA Annotated Table Z-1, www.osha.gov
      REL (Inhalation): Ca 0.015 mg/m3 (NIOSH)
      OSHA Annotated Table Z-1, www.osha.gov

8.2   Appropriate engineering controls
      Local exhaust ventilation or other engineering controls are normally required when handling or using this product to
      avoid overexposure.

8.3   Individual protection measures, such as personal protective equipment (PPE)

      Pictograms




      Eye/face protection
      Goggles

      Skin protection
      Gloves

      Body protection
      Labcoat

SECTION 9: Physical and chemical properties

      Information on basic physical and chemical properties




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Safety Data Sheet
Nickel Anode

     Appearance/form (physical state, color, etc.)           Solid sheet
     Odor                                                    None
     Odor threshold                                          No data available
     pH                                                      No data available
     Melting point/freezing point                            2651F
     Initial boiling point and boiling range                 5252F
     Flash point                                             na
     Evaporation rate                                        na
     Flammability (solid, gas)                               na
     Upper/lower flammability limits
     Vapor pressure                                          1mm Hg at 3290°F (1810°C)
     Vapor density                                           No data available
     Relative density                                        8.9 g/cc
     Solubility(ies)                                         Insoluble in water
     Partition coefficient: n-octanol/water                  No data available
     Auto-ignition temperature                               No data available
     Decomposition temperature                               No data available
     Viscosity                                               No data available
     Explosive properties                                    No data available
     Oxidizing properties                                    No data available

SECTION 10: Stability and reactivity

10.1 Reactivity
     Stable

10.2 Chemical stability
     Stable

10.3 Possibility of hazardous reactions
     High temperatures will generate toxic cadmium oxide fumes.

10.5 Incompatible materials
     Acids, aluminum alloys, ammonia, oxidizers, sulfur

SECTION 11: Toxicological information

     Information on toxicological effects

     Acute toxicity
     No data available

     Skin corrosion/irritation
     Repeated exposure may cause dermatitis.

     Serious eye damage/irritation
     No data available

     Respiratory or skin sensitization
     No data available




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Safety Data Sheet
Nickel Anode
    Germ cell mutagenicity
    No data available

    Carcinogenicity
    IARC NTP OSHA
    Listed Listed Listed

    Reproductive toxicity
    No data available

    Summary of evaluation of the CMR properties
    There is evidence of a sensitization effect. Target organ effects: certain forms of this product are considered
    carcinogens.

    STOT-single exposure
    No data available

    STOT-repeated exposure
    May cause dermatitis on exposed skin.

SECTION 12: Ecological information

    Toxicity
    96 HR LC50 BRACHYDANIO RERIO > 100 MG/L
    96 HR LC50 CYPRINUS CARPIO 10.4 MG/L (STATIC)
    48 HR EC50 DAPHNIA MAGNA > 100 MG/L
    48 HR EC50 DAPHNIA MAGNA > 1 MG/L (STATIC)
    72 HR EC50 PSEUDOKIRCHNERIELLA SUBCAPITATA 0.18 MG/L

    Other adverse effects
    Moderate ecological hazard. This product may be hazardous to plants and/or wildlife. Keep out or waterways.

SECTION 13: Disposal considerations

    Disposal of the product
    Dispose in accordance with all applicable Federal, State and Local regulations. Always contact a
    permitted waste disposer (TSD) to assure compliance

    Disposal of contaminated packaging
    Dispose in accordance with all applicable Federal, State and Local regulations. Always contact a
    permitted waste disposer (TSD) to assure compliance

SECTION 14: Transport information

    DOT (US)
    Not dangerous goods

    IMDG
    Not dangerous goods

    IATA




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Safety Data Sheet
Nickel Anode
     Not dangerous goods

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question
     Massachusetts Right To Know Components
     Chemical name: Nickel
     CAS number: 7440-02-0
     New Jersey Right To Know Components
     Common name: NICKEL
     CAS number: 7440-02-0
     Pennsylvania Right To Know Components
     Chemical name: Nickel
     CAS number: 7440-02-0
     California Prop. 65 components
     Chemical name: NICKEL POWDER
     CAS number: 7440-02-0
     10/01/1989 - Cancer

     HMIS Rating

                   Nickel Anode
       HEALTH                         3
       FLAMMABILITY                   0
       PHYSICAL HAZARD                0
       PERSONAL PROTECTION            C


     NFPA Rating




SECTION 16: Other information




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