CASWELL INC
Safety Data Sheet
Pickle #4
SECTION 1: Identification
1.1 Product identifier
Product name Pickle #4
Product number PIC4
Brand Caswell
1.2 Other means of identification
Tan Colored Powder
1.3 Recommended use of the chemical and restrictions on use
Metal Cleaner/Activator
1.4 Supplier's details
Name Caswell Inc
Address 7696 Route 31
Lyons NY 14489
USA
Telephone 315 946 1213
Fax 315 946 4456
email sales@caswellplating.com
1.5 Emergency phone number(s)
Office Hours (9-4ET): 315 946 1213
24 Hour: CHEMTEL US# 1-800-255-3924 Intl# +01-813-248-0585
SECTION 2: Hazard identification
2.1 Classification of the substance or mixture
- Eye damage/irritation (chapter 3.3), Cat. 1
- Skin corrosion/irritation (chapter 3.2), Cat. 2
- Acute toxicity, dermal (chapter 3.1), Cat. 3
2.2 GHS label elements, including precautionary statements
Pictogram
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Safety Data Sheet
Pickle #4
Signal word Danger
Hazard statement(s)
H318 Causes serious eye damage
H315 Causes skin irritation
H301 Toxic if swallowed
Precautionary statement(s)
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses if present and easy to do. Continue rinsing.
P264 Wash thoroughly after handling.
P302+P352 IF ON SKIN: Wash with plenty of water
P321 Specific treatment (see label).
P332+P313 If skin irritation occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P312 Call a POISON CENTER/doctor/... if you feel unwell.
P361+P364 Take off immediately all contaminated clothing and wash it before reuse.
P405 Store locked up.
P501 Dispose of contents/container per local regulations.
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Hazardous components
1. SODIUM HYDROGENSULPHATE
Concentration 90 - 90 % (weight)
EC no. 231-665-7
CAS no. 7681-38-1
Index no. 016-046-00-X
- Serious eye damage/eye irritation (chapter 3.3), Cat. 1
H318 Causes serious eye damage
2. SODIUM FLUORIDE
Concentration 10 - 10 % (weight)
EC no. 231-667-8
CAS no. 7681-49-4
Index no. 009-004-00-7
- Acute toxicity (chapter 3.1), Cat. 3
- Serious eye damage/eye irritation (chapter 3.3), Cat. 2
- Skin corrosion/irritation (chapter 3.2), Cat. 2
H301 Toxic if swallowed
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Safety Data Sheet
Pickle #4
H315 Causes skin irritation
H319 Causes serious eye irritation
SECTION 4: First-aid measures
4.1 Description of necessary first-aid measures
General advice Avoid contact. Wear protective clothing including eye protection and gloves
at all times.
If inhaled If breathed in, move person into fresh air. If not breathing, give artificial
respiration.
In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap
and plenty of water. Consult a physician
In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a
physician.Continue rinsing eyes during transport to hospital.
If swallowed Drink large quantities of water or milk. Follow with milk of magnesia, beaten
eggs or vegetable oil,. Do not induce vomiting. Contact physician
immediately.
SECTION 5: Fire-fighting measures
5.1 Suitable extinguishing media
Use extinguishing media appropriate for surrounding fire.
5.2 Specific hazards arising from the chemical
Product readily dissolves in water to form a weak sulfuric acid solution.
5.3 Special protective actions for fire-fighters
Wear self-contained breathing apparatus for firefighting if necessary.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Avoid breathing dust. Keep product dry and sweep up. Dispose of waste per all local and federal regulations.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Wear protective gear.
7.2 Conditions for safe storage, including any incompatibilities
Avoid strong alkaline materials such as caustic.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
1. SODIUM FLUORIDE (CAS: 7681-49-4)
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Safety Data Sheet
Pickle #4
TLV®: 2.5 mg/m3 of Flouride (OSHA)
8.3 Individual protection measures, such as personal protective equipment (PPE)
Body protection
Chemical Goggles, Chemical Resistant Gloves.
Respiratory protection
Wear NIOSH approved respirator appropriate for the vapor or mist at point of use.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Appearance/form (physical state, color, etc.) Tan Powder
Odor None
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability (solid, gas) None
Upper/lower flammability limits
Vapor pressure
Vapor density
Relative density 2.86
Solubility(ies) Water
Partition coefficient: n-octanol/water
Auto-ignition temperature
Decomposition temperature
Viscosity
Explosive properties
Oxidizing properties
SECTION 10: Stability and reactivity
10.2 Chemical stability
Stable
10.5 Incompatible materials
Strong alkaline materials
SECTION 11: Toxicological information
Information on toxicological effects
Acute toxicity
No data available
Skin corrosion/irritation
No data available
Serious eye damage/irritation
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Safety Data Sheet
Pickle #4
No data available
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
None
Reproductive toxicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
SECTION 12: Ecological information
Toxicity
No data available
SECTION 13: Disposal considerations
Disposal of the product
Consult appropriate federal and local regulations for disposal. Empty containers are subject to the same regulations.
SECTION 14: Transport information
DOT (US)
UN Number: UN1759
Class: 8
Packing Group: II
Proper Shipping Name: Corrosive Solid, NOS (Sodium Bisulfate)
Reportable quantity (RQ):
Marine pollutant:
Poison inhalation hazard:
Small Amounts May Be Considered Limited Quantities. Consult 49 CFR.
IMDG
UN Number:
Class:
Packing Group:
EMS Number:
Proper Shipping Name:
IATA
UN Number: UN1759
Class: 8
Packing Group: II
Proper Shipping Name: Corrosive Solid, NOS (Sodium Bisulfate)
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Safety Data Sheet
Pickle #4
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations specific for the product in question
Massachusetts Right To Know Components
Chemical name: Sodium fluoride
CAS number: 7681-49-4
New Jersey Right To Know Components
Common name: SODIUM FLUORIDE
CAS number: 7681-49-4
Pennsylvania Right To Know Components
Chemical name: Sodium fluoride
CAS number: 7681-49-4
HMIS Rating
Pickle #4
HEALTH *2
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION F
NFPA Rating
SECTION 16: Other information
16.1 Further information/disclaimer
DISCLAIMER: The information above is believed to be accurate and represents the best information currently
available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with
respect to such information, and we assume no liability resulting from its use. Users should make their own
investigation to determine the suitability of information for their particular purposes. In no event shall Caswell Inc be
liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental,
consequential or exemplary damages, whatsoever arising, even if Caswell Inc has been advised of the possibility of
such damages.
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