SAFETY DATA SHEET
Product: 1000-L
Revision Date: 6/01/2015
1. MATERIAL IDENTIFICATION
Product Name: Pyro-Putty 1000-L Liquid Binder
Product Description: Slightly Cloudy, Odorless Liquid
Product Use: High Temperature Adhesive/Coating Liquid Binder
Manufacturer: Aremco Products, Inc.
707-B Executive Blvd.
Valley Cottage, NY 10989
Telephone: 845-268-0039
Emergency Phone: 845-268-0039 or Infotrac (24/7) 800-535-5053
2. HAZARDS IDENTIFICATION
GHS Classification:
Eye Irritation Category 2A
Skin Irritation Category 2
GHS Symbol:
GHS Signal Word:
Warning
GHS Hazard Determining Component:
Silicate Solution
GHS Hazard Statements for Health Hazards:
H303 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
GHS Precautionary Statements - Prevention:
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves. Wear eye protection.
GHS Precautionary Statements – Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P332 + P313 If skin irritation occurs: Get medical advice/attention.
P305 + P351 + P338 IF IN EYES: Remove contact lenses, if present and easy to do. Rinse cautiously with water for several minutes.
P312 IF SWALLOWED: Call a poison center or doctor if you feel unwell
P362 Take off contaminated clothing and wash before reuse.
GHS Storage/Disposal:
P501 Dispose in accordance with local, regional, national or international regulations
3. COMPOSITION
Chemical Name CAS No. EC No. Concentration GHS Product Identifier
H302 Acute Toxicity, Oral, Cat 4
H315 Skin Corrosion/Irritation, Cat 2
Silicate Solution 1344-09-8 215-687-4 40.0-60.0%
H319 Eye Damage/Eye Irritation, Cat 2A
H335 STOT, SE; Respiratory Tract Irritation, Cat 3
Water 7732-18-5 NA 40.0-60.0% N/A
1
4. FIRST AID MEASURES
After eye contact: Hold eyelids open and flush with a steady, gentle stream of water for at least 15 minutes. Seek immediate
medical attention, preferably with an ophthalmologist.
After skin contact: Immediately wipe excess material off skin with a dry cloth then wash with soap and water for at least 5 minutes.
After inhalation: In case of inhalation due to spray mist, remove source of exposure and assure that victim is breathing. If not
breathing, administer cardio-pulmonary resuscitation (CPR).
After ingestion: If swallowed, do not induce vomiting. If victim is conscious and alert, give 1-2 glasses of water to drink. Do not
give anything by mouth to an unconscious person. Seek medical attention immediately.
Medical Conditions Possibly Inhalation of product may aggravate existing chromic respiratory problems such as asthma, emphysema or
Aggravated by Exposure: bronchitis. Skin contact may aggravate existing skin disease.
5. FIRE FIGHTING MEASURES
Extinguishing Media: This material is compatible with all extinguishing media.
Special Fire Fighting Procedures: Firefighters should wear NIOSH/MSHA approved positive pressure breathing apparatus with full face-piece and
full chemical resistant protective clothing. Dike area to prevent runoff and contamination of water sources.
Dispose of fire control water later.
Unusual Fire and Explosion Hazards: This material is non-combustible.
6. ACCIDENTAL RELEASE MEASURES
Personal Protection: Wear chemical goggles, body-covering protective clothing, chemical resistant gloves, and rubber boots. Use
NIOSH approved respirator where mist occurs.
Spill Cleanup: Mop up and neutralize liquid, then discharge to sewer in accordance with federal, state and local regulations or
permits. Flush area with water to complete cleanup. Exercise caution during neutralization as heat may be
generated.
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes, skin and clothing. Avoid breathing spray mist. Keep container closed. Promptly clean
residue from closures with cloth dampened with water. Promptly clean up spills.
Storage: Store in an area that is cool, dry, well ventilated, away from combustible material, and away from ignition
sources. Keep containers closed. Store in clean plastic or stainless steel containers.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
3 3
Chemical Name CAS No. EC No. TLV (mg/m ) PEL (mg/m )
Silicate Solution 1344-09-8 215-687-4 No available information No available information
Engineering Controls: Use with adequate ventilation. Keep containers closed. Safety shower and eyewash fountain should be within
direct access.
Respiratory Protection: This product is not considered respirable in either the liquid or cured forms. However, if the cured product is
polished, ground or chipped during processing, handling or use, powders may be released as airborne
respirable particles. In these instances, appropriate personal protection equipment and local ventilation controls
must be employed. If exposure limits are exceeded and local ventilation is unavailable, a supplied-air respirator
or a self-contained NIOSH-approved dust and mist respirator is required.
Skin Protection: Wear body-covering protective clothing and gloves.
Eye Protection: Wear chemical goggles.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and chemical here represent typical properties of this product. Contact Technical Sales for exact specifications.
Appearance: Liquid
Color: Slightly Cloudy
Odor Threshold: No available information
Odor: Odorless
pH: 11.0-11.5
Specific Gravity, g/cc 1.30-1.50
Water Solubility: Soluble
2
Melting Point: Not applicable
o
Boiling Point: 100 C
Vapor Pressure: Not applicable
Vapor Density (air=1): No data
VOC Content: 0.00 lbs/gal
Viscosity: < 500 cP
Decomposition Temperature: Not applicable
Auto-ignition Temperature Not applicable
Partition Coefficient: No data
Flash Point: Not applicable
Flammability: Not applicable
Evaporation Rate: Not applicable
10. STABILITY AND REACTIVITY
Chemical Stability: This material is stable under all conditions of use and storage.
Conditions to Avoid: Prolonged contact with aluminum, brass, copper, lead, and zinc may produce flammable hydrogen gas.
Materials to Avoid: Gels and heats when mixed with acid. May react with ammonium salts resulting in evolution of ammonia gas.
Hazardous Decomposition Products: None.
Hazardous Polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity: Component: Silicate Solution
LD50 Oral, 1153 mg/kg (Rat)
LD50, Inhalation, No Data
LD50, Dermal, 4640 mg/kg (Rabbit)
Skin Corrosion/Irritation: Irritating to skin
Serious Eye Damage/Irritation: Irritating to eyes
Sensitization: Not sensitizing
Mutagenicity: No data
Carcinogenicity: This product is not listed by IARC, NTP, OSHA, or ACGIH as a known or suspected carcinogen.
Reproductive Toxicity: No data
12. ECOLOGICAL INFORMATION
Ecotoxity: This material is believed to be practically non-toxic to aquatic life.
Biodegradation: This material is inorganic and not subject to biodegradation.
Persistence: this material is believed to persist in the environment.
Bioconcentration: This material is not expected to bioconcentrate in organisms.
Physical/Chemical: Sinks and mixes with water. Only water will evaporate from this material.
13. DISPOSAL CONSIDERATIONS
Disposal Method: Dispose in accordance with federal, state and local regulations and permits.
14. TRANSPORTATION INFORMATION
DOT UN Status: The material is not a regulated hazardous material for transportation.
15. REGULATORY INFORMATION
U.S. Federal Regulations
CERCLA: No CERCLA reportable quantity has been established for this material.
TSCA: All ingredients of this material are listed on the TSCA inventory.
3
SARA Title III
Sections 302, 304, 313: This product does not contain any substances reportable under these sections.
Sections 311, 312:
Hazard Classes Yes/No
Fire Hazard No
Reactivity Hazard No
Pressure Hazard No
Immediate Hazard Yes
Delayed Hazard No
International Inventory Status
Canada (DSL) Yes
Europe (EINECS/ELINCS) Yes
Australia (AICS) Yes
Japan (MITI) Yes
South Korea (KECL) Yes
16. OTHER INFORMATION
NFPA Ratings (scale 0 – 4) Health, 1
Flammability, 0
Reactivity, 0
Personal Protection, C
HMIS Ratings (scale 0 – 4) Health, 1
Flammability, 0
Reactivity, 0
Personal Protection, C
Key Legend Information
ACGIH American Conference of Governmental Industrial Hygienists
ARD International Agency for Research on Cancer
CAS Chemical Abstract Service
CERCLA Comprehensive Environmental Response, Compensation & Liability Act
DSL Domestic Substance List
EC European Commission
HMIS Hazardous Materials Identification System
IARC International Agency for Research on Cancer
ND Not Determined
NE Not Established
NFPA National Fire Protection Association
NIOSH National Institute for Occupational Safety & Health
NTP National Toxicology Program
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
RE Repeat Exposure
SARA Superfund Amendments & Reauthorization Act
SARA Title III Emergency Planning & Community Right to Know Act
SARA Section 302 Extremely Hazardous Substances
SARA Section 304 Emergency Release
SARA Section 311 MSDS/List of Chemicals & Hazardous Inventory
SARA Section 312 Emergency & Hazardous Inventory
SARA Section 313 Toxic Chemicals & Release Reporting
SE Single Exposure
STEL Short Term Exposure Limit
STOT Specific Target Organ Toxicity
TLV Threshold Limit Value
TWA Time Weighted Average
Disclaimer: The information contained herein is based on data taken from sources believed to be both current and reliable at the time of
publication. Aremco Products, Inc. makes no warranty, expressed or implied, as to the accuracy of this MSDS and assumes no liability arising from its
use by others. Compliance with all applicable Federal, State and Local laws and regulations remains the responsibility of the user.
4
SAFETY DATA SHEET
Product: 1000-P
Revision Date: 6/01/2015
1. MATERIAL IDENTIFICATION
Product Name: Pyro-Putty 1000-P
Product Description: Silver-Grey, Odorless Powder
Product Use: High Temperature Adhesive Powder
Manufacturer: Aremco Products, Inc.
707-B Executive Blvd.
Valley Cottage, NY 10989
Telephone: 845-268-0039
Emergency Phone: 845-268-0039 or Infotrac (24/7) 800-535-5053
2. HAZARDS IDENTIFICATION
GHS Classification:
Not classified.
GHS Symbol:
GHS Signal Word:
Warning
GHS Hazard Determining Component:
Aluminum
GHS Hazard Statements:
May form combustible dust concentrations in air. The powder does not meet the criteria for classification.
GHS Precautionary Statements - Prevention:
Prevent dust accumulation to minimize explosion hazard.
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P240 Ground/bond container and receiving equipment.
P242 Use only non-sparking tools.
P241 Use explosion-proof electrical/ventilating/lighting equipment.
P280 Wear protective gloves/eye protection/face protection.
P261 Avoid breathing dust.
GHS Precautionary Statements - Response:
P370 + P378 In case of fire: Use appropriate media to extinguish.
GHS Precautionary Statements – Storage/Disposal:
P402 + P404 Store in a dry place. Store in a closed container.
P501 Dispose in accordance with local, regional, national or international regulations.
3. COMPOSITION
Chemical Name CAS No. EC No. Concentration GHS Product Identifier
H228 Flammable Solids, Cat 1
Aluminum Powder 7429-90-5 231-072-3 90.0-100.0% H261 Substances & Mixtures Which, In Contact With
Water, Emit Flammable Gases, Cat 3
Alumino-Silicate 1332-58-7 310-194-1 1.0-10.0% H335 STOT, RE; Respiratory Tract Irritation, Cat 3
1
4. FIRST AID MEASURES
Eye Exposure: Hold eyelids open and flush with a steady, gentle stream of water for at least 15 minutes. Seek immediate
medical attention, preferably with an ophthalmologist. If a physician is not immediately available, eye irrigation
should be continued for an additional 15 minutes.
Skin Exposure: Immediately wipe excess material off skin with a dry cloth then wash with plenty of soap and water for at least 5
minutes. See medical attention if irritation develops or persists. Remove contaminated clothing and shoes and
clean thoroughly before re-use.
Inhalation: Remove from immediate source of exposure and assure that victim is breathing. If not breathing, administer
cardio-pulmonary resuscitation (CPR). If breathing is difficult, administer oxygen if available. Seek medical
attention.
Ingestion: If swallowed, do not induce vomiting. If victim is conscious and alert, give 1-2 glasses of water to drink. Do not
give anything by mouth to an unconscious person. Seek medical attention immediately. Do not leave victim
unattended. To prevent aspiration of swallowed product, lay victim on side with head lower than waist.
Vomiting may occur spontaneously. If vomiting occurs and the victim is conscious, give water to further dilute
the chemical.
Medical Conditions Possibly Inhalation of product may aggravate existing chromic respiratory problems such as asthma, emphysema or
Aggravated by Exposure: bronchitis. Skin contact may aggravate existing skin disease.
5. FIRE FIGHTING MEASURES
Extinguishing Media: Dry chemical, carbon dioxide, and foam.
Special Fire Fighting Procedures: Gently cover the burning powder and form a ring around it with the extinguishing agents recommended.
Do not actually mix the agent with the burning powder and do not disturb the powder until it cools to ambient
temperature. At no time should dust clouds be allowed to form. Firefighters should wear NIOSH/MSHA
approved positive pressure breathing apparatus with full face-piece and full chemical resistant protective
clothing. Dike area to prevent runoff and contamination of water sources. Dispose of fire control water later.
Unusual Fire & Explosion Hazards: Class “D” dry chemical extinguishing agent or other suitable extinguishing material such as dry sand. Do not
use Class “A”, “B” or “C” extinguishers or halogenated agents. Do not use water. Water and burning finely
divided aluminum react violently forming hydrogen gas and aluminum oxide. Aluminum particles will burn at a
very high temperature as a mass of material or be potentially explosive if loosened and dispersed in air. At no
time should a dust cloud be allowed to form. This material is potentially explosive when loosened and
dispersed in air. Follow the listed fire fighting procedures carefully and refer to the Aluminum Association TR-2
Bulletin.
Hazardous Decomposition Materials: Aluminum reacts with water, acids or alkalis to form combustible hydrogen gas.
6. ACCIDENTAL RELEASE MEASURES
Personal Protection: Wear chemical goggles, body-covering protective clothing, chemical resistant gloves, and rubber boots. Use
NIOSH approved respirator where mist occurs.
Spill Cleanup: Remove all ignition sources. Keep people away. Avoid exposure to sparks, fire or hot metal surfaces. Use
non-sparking tools and transfer spilled material to a leak proof container for disposal in accordance with federal,
state and local regulations or permits.
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes, skin and clothing. Avoid breathing spray mist. Keep container closed. Promptly clean
residue from closures with cloth dampened with water. Promptly clean up spills.
Storage: Store in an area that is cool, dry, well ventilated, away from combustible material, and away from ignition
sources. Keep containers closed. Store in clean plastic or stainless steel containers.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
3 3
Chemical Name CAS No. EC No. PEL (mg/m ) TLV (mg/m )
Aluminum Powder, Stabilized 7429-90-5 231-072-3 5 5
Alumino-Silicate 1332-58-7 310-194-1 No available information 5
Engineering Controls: Use with adequate ventilation. Exhaust fan should be explosion proof. Keep containers closed. Safety shower
and eyewash fountain should be within direct access. No smoking or open lights.
Respiratory Protection: If exposure limits are exceeded and local ventilation is unavailable, a supplied-air respirator or a self-contained
NIOSH-approved dust and mist respirator is required.
Skin Protection: Wear body-covering protective clothing and gloves.
Eye Protection: Wear chemical goggles.
2
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and chemical here represent typical properties of this product. Contact Technical Sales for detailed specifications.
Appearance: Powder
Color: Silver-Grey
Odor: Odorless
Odor Threshold: Not available
pH: Not available
Melting/Freezing Point: Not available
Boiling Point Range: Not available
Flash Point: Not available
Evaporation Rate: Not available
Flammability: Not available
Flammability Limits: Not available
Vapor Pressure: Not available
Vapor Density: Not available
Relative Density: Not available
Solubility (water): None
Auto-Ignition Temperature: 1094 F (590 C)
Decomposition Temperature: Not available
Specific Gravity, g/cc: 2.5-2.7
Vapor Density (air=1): Heavier than air
VOC Content, g/l: 0.00
10. STABILITY AND REACTIVITY
Chemical Stability: This material is stable under normal storage conditions.
Conditions to Avoid: Heat, sparks, and open flames.
Materials to Avoid: Water, acids, alkalis, chlorinated hydrocarbons and strong oxidizers.
Hazardous Decomposition Products: Combustible hydrogen gas.
Hazardous Polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure:
Inhalation: Dust may irritate respiratory system. Prolonged inhalation may be harmful.
Skin: Dust or powder may irritate the skin.
Eye: Dust may irritate the eyes.
Ingestion: Harmful if swallowed.
Symptoms related to the physical, Dusts may irritate the respiratory tract, skin and eyes.
chemical and toxicological
characteristics:
Information on toxicological effects:
Acute Toxicity: Not available.
Skin Corrosion/Irritation: Not expected to be hazardous by OSHA criteria. Due to lack of data the classification is not possible.
Serious Eye Damage/Irritation: Due to lack of data the classification is not possible.
Respiratory Sensitization: Due to lack of data the classification is not possible.
Skin Sensitization: This product is not expected to cause skin sensitization.
Germ Cell Mutagenicity: Due to lack of data the classification is not possible.
Carcinogenicity: Not expected to be hazardous by WHMIS criteria. Not expected to be hazardous by OSHA criteria. This
product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Reproductive Toxicity: Not expected to be hazardous by OSHA criteria. Due to lack of data the classification is not possible.
STOT, Single Exposure: Due to lack of data the classification is not possible.
STOT, Repeated Exposure: May cause damage to organs through prolonged or repeated exposure.
Aspiration Hazard: Due to lack of data the classification is not possible.
Chronic Effects: Not expected to be hazardous by WHMIS criteria. Hazardous by OSHA criteria. Prolonged inhalation may be
harmful. Prolonged exposure may cause chronic effects.
Further Information: This product has no known adverse effect on human health.
3
12. ECOLOGICAL INFORMATION
Ecotoxity: Ecological injuries are not known or expected under normal use.
Persistence & Degradability: Not available.
Bioaccumulative Potential: Not available.
Mobility in Soil: Not available.
Other Adverse Effects: Not available.
13. DISPOSAL CONSIDERATIONS
Disposal Method: Dispose in accordance with federal, state and local regulations and permits.
14. TRANSPORTATION INFORMATION
DOT UN Status: This material is not a regulated hazardous material for transportation.
15. REGULATORY INFORMATION
U.S. Federal Regulations
CERCLA: No CERCLA reportable quantity has been established for this material.
TSCA: All ingredients of this material are listed on the TSCA inventory.
SARA Title III
Sections 302, 304, 313: This product does not contain any substances reportable under these sections.
Sections 311, 312:
Hazard Classes Yes/No
Fire Hazard No
Reactivity Hazard No
Pressure Hazard No
Immediate Hazard No
Delayed Hazard No
International Inventory Status
Canada (DSL) Yes
Europe (EINECS/ELINCS) Yes
Australia (AICS) Yes
Japan (MITI) Yes
South Korea (KECL) Yes
4
16. OTHER INFORMATION
Key Legend Information
ACGIH American Conference of Governmental Industrial Hygienists
ARD International Agency for Research on Cancer
CAS Chemical Abstract Service
CERCLA Comprehensive Environmental Response, Compensation & Liability Act
DSL Domestic Substance List
EC European Commission
HMIS Hazardous Materials Identification System
IARC International Agency for Research on Cancer
ND Not Determined
NE Not Established
NFPA National Fire Protection Association
NIOSH National Institute for Occupational Safety & Health
NTP National Toxicology Program
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
RE Repeat Exposure
RTECS Registry of Toxic Effects of Chemical Substances
SARA Superfund Amendments & Reauthorization Act
SARA Title III Emergency Planning & Community Right to Know Act
SARA Section 302 Extremely Hazardous Substances
SARA Section 304 Emergency Release
SARA Section 311 MSDS/List of Chemicals & Hazardous Inventory
SARA Section 312 Emergency & Hazardous Inventory
SARA Section 313 Toxic Chemicals & Release Reporting
SE Single Exposure
STEL Short Term Exposure Limit
STOT Specific Target Organ Toxicity
TLV Threshold Limit Value
TWA Time Weighted Average
Disclaimer: The information contained herein is based on data taken from sources believed to be both current and reliable at the time of publication.
Aremco Products, Inc. makes no warranty, expressed or implied, as to the accuracy of this MSDS and assumes no liability arising from its use by
others. Compliance with all applicable Federal, State and Local laws and regulations remains the responsibility of the user.
5