Safety Data Sheet
Specialty Green AEN
Date: 03/25/2015 Version: 1
1. Identification
1.1. Product identifier
Product Identity Specialty Green AEN
Alternate Names Specialty Green AEN
1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use Dye used to color anodized aluminum.
Application Method See Technical Data Sheet.
1.3. Details of the supplier of the safety data sheet
Company Name U.S. Specialty Color Corporation
5624 Cannon Drive
Monroe, NC 28110
Emergency
24 hour Emergency Telephone No. 1-800-424-9300
Customer Service: U.S. Specialty Color Corporation 704-292-1476
2. Hazard(s) identification
2.1. Classification of the substance or mixture
Acute Tox. 4;H302 Harmful if swallowed.
2.2. Label elements
Using the Toxicity Data listed in section 11 and 12 the product is labeled as follows.
Warning
H302 Harmful if swallowed.
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Safety Data Sheet
Specialty Green AEN
Date: 03/25/2015 Version: 1
[Prevention]:
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
[Response]:
P301+312 IF SWALLOWED: Call a POISON CENTER or doctor / physician if you feel unwell.
P330 Rinse mouth.
[Storage]:
No GHS storage statements
[Disposal]:
P501 Dispose of contents / container in accordance with local / national regulations.
3. Composition/information on ingredients
This product contains the following substances that present a hazard within the meaning of the relevant State and
Federal Hazardous Substances regulations.
Ingredient/Chemical Designations Weight % GHS Classification Notes
Anthraquinone / Azo dyes 85 - 100 Acute Tox. 4;H302 [1]
CAS Number: Proprietary
Sodium Sulfate, Anhydrous 10 - 25 Not Classified [1]
CAS Number: 0007757-82-6
In accordance with paragraph (i) of ยง1910.1200, the specific chemical identity and/or exact percentage (concentration) of composition has been
withheld as a trade secret.
[1] Substance classified with a health or environmental hazard.
[2] Substance with a workplace exposure limit.
[3] PBT-substance or vPvB-substance.
*The full texts of the phrases are shown in Section 16.
4. First aid measures
4.1. Description of first aid measures
General In all cases of doubt, or when symptoms persist, seek medical attention.
Never give anything by mouth to an unconscious person.
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Specialty Green AEN
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Inhalation Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped,
give artificial respiration. If unconscious place in the recovery position and obtain
immediate medical attention. Give nothing by mouth.
Eyes Irrigate copiously with clean water for at least 15 minutes, holding the eyelids apart and
seek medical attention.
Skin Remove contaminated clothing. Wash skin thoroughly with soap and water or use a
recognized skin cleanser.
Ingestion If the person has inadvertently swallowed some of the material and they are conscious, try
to induce vomiting. Never make an unconscious person vomit. Obtain medical attention
immediately.
4.2. Most important symptoms and effects, both acute and delayed
Overview Health effects of exposure:
Inhalation: Inhalation of dust may cause respiratory irritation.
Ingestion: May cause gastric disturbances.
Skin: May cause irritation to skin.
Eyes: Contact may cause irritation.
See section 2 for further details.
Ingestion Harmful if swallowed.
5. Fire-fighting measures
5.1. Extinguishing media
Recommended extinguishing media; CO2, powder, water
5.2. Special hazards arising from the substance or mixture
Hazardous composition products: Burning may produce oxides of carbon, nitrogen and sulfur.
5.3. Advice for fire-fighters
Unusual fire/explosion hazards: Organic dusts have potential to be explosive with static spark or flame initiation.
Adequate ventilation and clean-up must be maintained to minimize dust accumulation.
Fire-fighters should wear appropriate equipment and self-contained breathing apparatus (SCBA) with a full face-
piece operated in positive pressure mode.
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Specialty Green AEN
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ERG Guide No. ----
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Put on appropriate personal protective equipment (see section 8).
6.2. Environmental precautions
Do not allow spills to enter drains or waterways.
Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove
soiled clothing and wash thoroughly before reuse.
6.3. Methods and material for containment and cleaning up
Wear prescribed protective equipment. Vacuum or sweep up material and place in a designated container
immediately. Prevent run off to drains, sewers or other public waterways.
Waste material may be disposed of by a licensed waste facility contractor.
7. Handling and storage
7.1. Precautions for safe handling
Avoid contact with eyes, skin, and clothing. Eating, drinking, and smoking should be prohibited in areas where this
material is handled. Wash hands and face before eating, drinking, and smoking. Put on appropriate personal
protective equipment (see section 8).
See section 2 for further details. - [Prevention]:
7.2. Conditions for safe storage, including any incompatibilities
Handle containers carefully to prevent damage and spillage.
Do not expose to friction or shock.
Incompatible materials: Strong reducing agents.
Store in original container, in a cool, dry location. Close package tightly after removal of product. Avoid dust
formation. Keep away from sources of ignition.
See section 2 for further details. - [Storage]:
7.3. Specific end use(s)
No data available.
8. Exposure controls and personal protection
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Safety Data Sheet
Specialty Green AEN
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8.1. Control parameters
Exposure
CAS No. Ingredient Source Value
0007757-82-6 Sodium Sulfate, Anhydrous OSHA No Established Limit
ACGIH No Established Limit
NIOSH No Established Limit
Supplier No Established Limit
Proprietary Anthraquinone / Azo dyes OSHA No Established Limit
ACGIH No Established Limit
NIOSH No Established Limit
Supplier No Established Limit
The exposure limits for nuisance dust are: OSHA PEL: 15 mg/m3 (50 mppcf*) TWA, ACGIH 10 mg/m3.
Carcinogen Data
CAS No. Ingredient Source Value
0007757-82-6 Sodium Sulfate, Anhydrous OSHA Select Carcinogen: No
NTP Known: No; Suspected: No
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
Proprietary Anthraquinone / Azo dyes OSHA Select Carcinogen: No
NTP Known: No; Suspected: No
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
8.2. Exposure controls
Respiratory An appropriate NIOSH approved respirator for dust should be worn. Use type N95 (US) or
type P1 (EN 143) dust masks.
Eyes Wear safety glasses with side shields.
Skin Wear a rubber or plastic apron. Wear clothing suitable to avoid skin contact and clean after
every shift. Wear impermeable rubber or plastic gloves.
Engineering Controls Provide adequate ventilation. Where reasonably practicable this should be achieved by the
use of local exhaust ventilation and good general extraction. If these are not sufficient to
maintain concentrations of particulates and any vapor below occupational exposure limits
suitable respiratory protection must be worn.
Other Work Practices Eye wash fountain and emergency showers are recommended. Use good personal
hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly
remove soiled clothing and wash thoroughly before reuse.
See section 2 for further details. - [Prevention]:
9. Physical and chemical properties
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Safety Data Sheet
Specialty Green AEN
Date: 03/25/2015 Version: 1
Appearance Green Powder
Odor Not Specified
Odor threshold Not Measured
pH Not Measured
Melting point / freezing point Not Measured
Initial boiling point and boiling range Not Measured
Flash Point Not Measured
Evaporation rate (Ether = 1) Not Measured
Flammability (solid, gas) Not Applicable
Upper/lower flammability or explosive limits Lower Explosive Limit: Not Measured
Upper Explosive Limit: Not Measured
Vapor pressure (Pa) Not Measured
Vapor Density Not Measured
Specific Gravity Not Measured
Solubility in Water Approximately 50 g/l (72F)
Partition coefficient n-octanol/water (Log Kow) Not Measured
Auto-ignition temperature Not Measured
Decomposition temperature Not Measured
Viscosity (cSt) Not Measured
9.2. Other information
No other relevant information.
10. Stability and reactivity
10.1. Reactivity
Hazardous Polymerization will not occur.
10.2. Chemical stability
Stable under normal circumstances.
10.3. Possibility of hazardous reactions
No data available.
10.4. Conditions to avoid
No data available.
10.5. Incompatible materials
Strong reducing agents.
10.6. Hazardous decomposition products
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Safety Data Sheet
Specialty Green AEN
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When used and handled as directed, none.
11. Toxicological information
Acute toxicity
Ingredient Oral LD50, Skin LD50, Inhalation Inhalation Inhalation
mg/kg mg/kg Vapor LC50, Dust/Mist Gas LC50,
mg/L/4hr LC50, ppm
mg/L/4hr
Anthraquinone / Azo dyes - (Proprietary) No data No data No data No data No data
available available available available available
Sodium Sulfate, Anhydrous - (7757-82-6) No data No data No data No data No data
available available available available available
Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate
was used in the calculation of the product's ATE (Acute Toxicity Estimate).
Classification Category Hazard Description
Acute toxicity (oral) 4 Harmful if swallowed.
Acute toxicity (dermal) --- Not Applicable
Acute toxicity (inhalation) --- Not Applicable
Skin corrosion/irritation --- Not Applicable
Serious eye damage/irritation --- Not Applicable
Respiratory sensitization --- Not Applicable
Skin sensitization --- Not Applicable
Germ cell mutagenicity --- Not Applicable
Carcinogenicity --- Not Applicable
Reproductive toxicity --- Not Applicable
STOT-single exposure --- Not Applicable
STOT-repeated exposure --- Not Applicable
Aspiration hazard --- Not Applicable
12. Ecological information
12.1. Toxicity
No additional information provided for this product. See Section 3 for chemical specific data.
Aquatic Ecotoxicity
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Safety Data Sheet
Specialty Green AEN
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96 hr LC50 fish, 48 hr EC50 crustacea, ErC50 algae,
Ingredient
mg/l mg/l mg/l
Anthraquinone / Azo dyes - (Proprietary) Not Available Not Available Not Available
Sodium Sulfate, Anhydrous - (7757-82-6) Not Available Not Available Not Available
12.2. Persistence and degradability
There is no data available on the preparation itself.
12.3. Bioaccumulative potential
Not Measured
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB assessment
This product contains no PBT/vPvB chemicals.
12.6. Other adverse effects
No data available.
13. Disposal considerations
13.1. Waste treatment methods
Observe all federal, state and local regulations when disposing of this substance.
14. Transport information
DOT (Domestic Surface IMO / IMDG (Ocean ICAO/IATA
Transportation) Transportation)
14.1. UN number Not Applicable Not Regulated Not Regulated
14.2. UN proper shipping Not Regulated Not Regulated Not Regulated
name
14.3. Transport hazard DOT Hazard Class: Not IMDG: Not Applicable Air Class: Not Applicable
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Safety Data Sheet
Specialty Green AEN
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class(es) Applicable Sub Class: Not Applicable
14.4. Packing group Not Applicable Not Applicable Not Applicable
14.5. Environmental hazards
IMDG Marine Pollutant: No
14.6. Special precautions for user
No further information
15. Regulatory information
Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected
regulations are represented.
Toxic Substance All components of this material are either listed or exempt from listing on the TSCA
Control Act ( TSCA) Inventory.
WHMIS Classification Not Regulated
US EPA Tier II Hazards Fire: No
Sudden Release of Pressure: No
Reactive: No
Immediate (Acute): Yes
Delayed (Chronic): No
EPCRA 311/312 Chemicals and RQs:
To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
EPCRA 302 Extremely Hazardous:
To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
EPCRA 313 Toxic Chemicals:
To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
Proposition 65 - Carcinogens (>0.0%):
To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
Proposition 65 - Developmental Toxins (>0.0%):
To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
Proposition 65 - Female Repro Toxins (>0.0%):
To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
Proposition 65 - Male Repro Toxins (>0.0%):
To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
New Jersey RTK Substances (>1%) :
To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
Pennsylvania RTK Substances (>1%):
Sodium Sulfate, Anhydrous
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Safety Data Sheet
Specialty Green AEN
Date: 03/25/2015 Version: 1
16. Other information
The information and recommendations contained herein are based upon data believed to be correct. However, no
guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein.
We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our
products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and
orders.
The full text of the phrases appearing in section 3 is:
H302 Harmful if swallowed.
This is the first version in the GHS SDS format. Listings of changes from previous versions in other formats
are not applicable.
We believe all the data and information given is accurate as of the date of preparation and is offered in good faith, but
without warranty or representation. Since conditions of use are beyond our control, we disclaim all liability for reliance
thereon. This is offered solely for your consideration, investigation and verification.
End of Document
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