CASWELL INC
Safety Data Sheet
Tin Plating Concentrate
SECTION 1: Identification
1.1 Product identifier
Product name Tin Plating Concentrate
Product number TINCON
Brand Caswell
1.2 Other means of identification
Plug N Plate Tin Solution
1.3 Recommended use of the chemical and restrictions on use
Electroplating Bath
1.4 Supplier's details
Name Caswell Inc
Address 7696 Route 31
Lyons NY 14489
USA
Telephone 315 946 1213
Fax 315 946 4456
email sales@caswellplating.com
1.5 Emergency phone number(s)
Office Hours (9-4ET): 315 946 1213
24 Hour: CHEMTEL US# 1-800-255-3924 Intl# +01-813-248-0585
SECTION 2: Hazard identification
2.1 Classification of the substance or mixture
- Skin corrosion/irritation (chapter 3.2), Cat. 1B
- Germ cell mutagenicity (chapter 3.5), Cat. 2
- Corrosive to metals (chapter 2.16), Cat. 1
- Eye damage/irritation (chapter 3.3), Cat. 2A
- Sensitization, skin (chapter 3.4), Cat. 1A
- Hazardous to the aquatic environment - long-term hazard (chapter 4.1), Cat. 1
- Acute toxicity, inhalation (chapter 3.1), Cat. 4
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Tin Plating Concentrate
- Specific target organ toxicity, single exposure (chapter 3.8), Cat. 3
- Specific target organ toxicity, repeated exposure (chapter 3.9), Cat. 2
2.2 GHS label elements, including precautionary statements
Pictogram
Signal word Warning
Hazard statement(s)
H314 Causes severe skin burns and eye damage
H341 Suspected of causing genetic defects
H317 May cause an allergic skin reaction
H290 May be corrosive to metals
H319 Causes serious eye irritation
H410 Very toxic to aquatic life with long lasting effects
H332 Harmful if inhaled
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H373 May cause damage to organs through prolonged or repeated exposure
Precautionary statement(s)
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P363 Wash contaminated clothing before reuse.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P310 Immediately call a POISON CENTER/doctor/...
P321 Specific treatment (see … on this label).
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses if present and easy to do. Continue rinsing.
P405 Store locked up.
P501 Dispose of contents/container to …
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P333+P313 If skin irritation or a rash occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P234 Keep only in original container.
P390 Absorb spillage to prevent material damage.
P406 Store in a corrosive resistant/… container with a resistant inner liner.
P337+P313 If eye irritation persists: Get medical advice/attention.
P273 Avoid release to the environment.
P391 Collect spillage.
P271 Use only outdoors or in a well-ventilated area.
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Tin Plating Concentrate
P312 Call a POISON CENTER/doctor/... if you feel unwell.
P403+P233 Store in a well ventilated place. Keep container tightly closed.
P314 Get medical advice/attention if you feel unwell.
SECTION 3: Composition/information on ingredients
3.1 Substances
Hazardous components
1. Tin (II) Sulfate
Concentration 19 %
CAS no. 7488-55-3
2. Sulfuric acid (<10%)
Concentration 2%
EC no. 231-639-5
CAS no. 7664-93-9
Index no. 016-020-00-8
3. WATER OR OTHER NON-REPORTABLE INGREDIENTS
Concentration 79 %
CAS no. 7732-18-5
SECTION 4: First-aid measures
4.1 Description of necessary first-aid measures
General advice Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled If breathed in, move person into fresh air. If not breathing, give artificial
respiration. Consult a physician.
In case of skin contact Rinse with plenty of water. Get medical attention if irritation develops and
persists.
In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a
physician.
If swallowed Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical
attention immediately if symptoms occur.
Personal protective equipment for first-aid responders
See section 8
4.2 Most important symptoms/effects, acute and delayed
Material is destructive to mucous membranes and upper respiratory tract, eyes and skin. Inhalation may be fatal as
a result of spasm, inflammation and edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema.
SECTION 5: Fire-fighting measures
5.1 Suitable extinguishing media
Use extinguishing media appropriate for surrounding fire.
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Tin Plating Concentrate
5.2 Specific hazards arising from the chemical
None Known
5.3 Special protective actions for fire-fighters
Wear self-contained breathing apparatus for firefighting if necessary.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Wear PPE per section 8.
6.2 Environmental precautions
Avoid release into the environment.
6.3 Methods and materials for containment and cleaning up
SMALL SPILLS: Contain and absorb with absorbent material and place into containers for later disposal. Wash site
of spillage thoroughly with water. LARGE SPILLS: Dike far ahead of spill to prevent further movement. Recover by
pumping or by using a suitable absorbent material and place into containers for later disposal. Dispose in suitable
waste container.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully
resealed and kept upright to prevent leakage.
7.2 Conditions for safe storage, including any incompatibilities
Keep away from oxidizers.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
1. Tin (II) Sulfate (CAS: 7488-55-3)
PEL-TWA: 2mg/m3 (OSHA)
2. Sulfuric acid (<10%) (CAS: 7664-93-9 EC: 231-639-5)
PEL-TWA: 1mg/m3 (OSHA)
8.2 Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.
8.3 Individual protection measures, such as personal protective equipment (PPE)
Eye/face protection
Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Wear chemical resistant gloves and clothing.
Body protection
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Tin Plating Concentrate
Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the
specific work-place., The type of protective equipment must be selected according to the concentration and amount
of the dangerous substance at the specific workplace.
Respiratory protection
NIOSH/MSHA approved air purifying respirator with an organic vapor cartidge or canister may be permissable
under certain circumstances where airborne concentrations are expected to exceed exposure limits.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Appearance/form (physical state, color, etc.) White liquid
Odor None
Odor threshold
pH 1
Melting point/freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability limits
Vapor pressure
Vapor density
Relative density 1.3
Solubility(ies) Fully miscible in water
Partition coefficient: n-octanol/water
Auto-ignition temperature
Decomposition temperature
Viscosity
Explosive properties
Oxidizing properties
SECTION 10: Stability and reactivity
10.1 Reactivity
No reactive
10.2 Chemical stability
Stable
10.5 Incompatible materials
Strong Oxidizers
10.6 Hazardous decomposition products
Sulfur oxides, Tin/Tin Oxides
SECTION 11: Toxicological information
Information on toxicological effects
Acute toxicity
Harmful if swallowed, inhaled or absorbed through skin. Material is destructive to mucous membranes and upper
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respiratory tract, eyes and skin. Inhalation may be fatal as a result of spasm, inflammation and edema of the larynx
and bronchi, chemical pneumonitis and pulmonary edema.
LD50 Oral Rat - 2207 mh/kg (Tin Sulfate)
LC50 Inhalation Rat 4 hour > 2mg/l
Skin corrosion/irritation
Can cause burns and irritation.
Serious eye damage/irritation
Causes serious eye irritation.
Respiratory or skin sensitization
May be absorbed through skin in harmful amounts.
Germ cell mutagenicity
Suspected of causing genetic problems.
Carcinogenicity
Not a carcinogen
STOT-single exposure
Respiratory Systen
STOT-repeated exposure
Cardi Vascular System
SECTION 12: Ecological information
Toxicity
Harmful to the environment.
LC50 - Daphnia Magna 99.5 mg/l - 48 hour (Tin Sulfate)
SECTION 13: Disposal considerations
Disposal of the product
Consult appropriate federal and local regulations for disposal. Empty containers are subject to the same regulations.
Disposal of contaminated packaging
Consult appropriate federal and local regulations for disposal. Empty containers are subject to the same regulations.
SECTION 14: Transport information
DOT (US)
UN Number: UN3264
Class: 8
Packing Group: II
Proper Shipping Name: Corrosive liquid, acidic, n.o.s. (Sulfuric Acid)
Reportable quantity (RQ):
Marine pollutant:
Poison inhalation hazard:
Quantities under 1 L may be shipped as LTD QTY
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Tin Plating Concentrate
IMDG
UN Number: UN3264
Class: 8
Packing Group: II
EMS Number:
Proper Shipping Name: Corrosive liquid, acidic, n.o.s. (Sulfuric Acid)
IATA
UN Number: UN3264
Class: 8
Packing Group: II
Proper Shipping Name: Corrosive liquid, acidic, n.o.s. (Sulfuric Acid)
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations specific for the product in question
Massachusetts Right To Know Components
Chemical name: Sulfuric acid
CAS number: 7664-93-9
New Jersey Right To Know Components
Common name: SULFURIC ACID
CAS number: 7664-93-9
Pennsylvania Right To Know Components
Chemical name: Sulfuric acid
CAS number: 7664-93-9
California Prop. 65 components
Chemical name: Sulfuric acid (<10%)
CAS number: 7664-93-9
03/14/2003 - Cancer
HMIS Rating
Tin Plating Concentrate
HEALTH *2
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION C
NFPA Rating
SECTION 16: Other information
16.1 Further information/disclaimer
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Safety Data Sheet
Tin Plating Concentrate
DISCLAIMER: The information above is believed to be accurate and represents the best information currently
available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with
respect to such information, and we assume no liability resulting from its use. Users should make their own
investigation to determine the suitability of information for their particular purposes. In no event shall Caswell Inc be
liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental,
consequential or exemplary damages, whatsoever arising, even if Caswell Inc has been advised of the possibility of
such damages.
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